Abstract
A new method of determination of the isothermic compressibility coefficient of a solvent from a change in the absorbance of a solution of the dye under elevated pressure (up to 100 MPa) was proposed. The method was checked by comparison with the known data for carbon tetrachloride and toluene at 25 °C.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
S. D. Hamann, Ann. Rev. Phys. Chem., 1964, 15, 349.
A. T. J. Hayward, J. Phys. D: Appl. Phys., 1971, 4, 938.
N. S. Isaacs, Liquid Phase High Pressure Chemistry, Wiley-Interscience, Chichester-New York-Brisbane-Toronto, 1981, 414 pp.
W. J. le Noble, Organic High Pressure Chemistry, Elsevier, Amsterdam-Oxford-New York-Tokyo, 1988, 489 pp.
V. D. Kiselev, E. A. Kashaeva, G. G. Iskhakova, L. N. Potapova, and A. I. Konovalov, J. Phys. Org. Chem., 2006, 19, 179.
Y. Marcus and G. T. Hefter, J. Mol. Liquids, 1997, 73–74, 61.
V. D. Kiselev, E. A. Kashaeva, and A. I. Konovalov, Tetrahedron, 1999, 55, 1153.
Author information
Authors and Affiliations
Corresponding author
Additional information
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2049–2052, December, 2006.
Rights and permissions
About this article
Cite this article
Kiselev, V.D., Bolotov, A.V., Kashaeva, E.A. et al. Determination of isothermic compressibility of solvent from changes in the absorbance of a dye solution under pressure. Russ Chem Bull 55, 2129–2132 (2006). https://doi.org/10.1007/s11172-006-0563-x
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11172-006-0563-x