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Synthesis and electrochemical study of 2-(2-pyridyl)benzothiazole complexes with transition metals (CoII, NiII, and CuII). Molecular structure of aquabis[2-(2-pyridyl)benzothiazole]copper(II) diperchlorate

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Abstract

The reactions of 2-(2-pyridyl)benzothiazole (1) with MX2·nH2O salts (M = NiII, CoII, or CuII; X = Cl or ClO4; n = 0–2) in EtOH afforded the corresponding complexes. Depending on the nature of the counterion in the starting metal salt, the reactions give compounds of composition M(1)Cl2·nH2O or Cu(1)2(ClO4)2·H2O. The molecular and crystal structure of the CuII(1)2(ClO4)2·H2O complex was established by X-ray diffraction. The copper atom in this complex has a distorted tetragonal-pyramidal ligand environment and is coordinated by four nitrogen atoms of two ligand molecules and one water molecule. Electrochemical study of the ligand and the resulting complexes by cyclic voltammetry and at a rotating disk electrode demonstrated that ligand 1 stabilizes reduced forms of complexes containing Ni, Co, or Cu atoms in the oxidation state +1.

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References

  1. X.-F. He, C. M. Vogels, A. Decken, and S. A. Westcott, Polyhedron, 2004, 23, 155.

    Article  CAS  Google Scholar 

  2. H. Sheng-Zhu, S. Dashuang, H. Taishan, W. Jiazhu, H. Zexing, X. Jinlong, and X. Chenghui, Inorg. Chim. Acta, 1990, 173, 1.

    Article  Google Scholar 

  3. M. Maji, P. Sengupta, S. K. Chattopadhyay, B. Mostafa, C. H. Schwalbe, and S. Ghosh, J. Coord. Chem., 2001, 54, 13.

    CAS  Google Scholar 

  4. B. K. Panda, K. Ghosh, S. Chattopadhyay, and A. Chakravorty, J. Organomet. Chem., 2003, 674, 107.

    Article  CAS  Google Scholar 

  5. S. Sengupta, J. Gangopadhyay, and A. Chakravorty, J. Chem. Soc., Dalton Trans., 2003, 4635.

  6. J. Gangopadhyay, S. Sengupta, S. Bhattacharyya, I. Chakraboty, and A. Chakravorty, Inorg. Chem., 2002, 41, 2616.

    Article  CAS  Google Scholar 

  7. X. Chen, F. J. Femia, J. W. Babich, and J. Zubieta, Inorg. Chim. Acta, 2001, 314, 91.

    Article  CAS  Google Scholar 

  8. J. L. Corbin and D. E. Work, Can. J. Chem., 1974, 52, 1054.

    Article  CAS  Google Scholar 

  9. D. Zhu, Y. Xu, Y. Mei, Y. Sci, C. Tu, and X. You, J. Mol. Struct., 2001, 559, 119.

    Article  CAS  Google Scholar 

  10. L. Zhang, L. Liu, D. Jia, and K. Yu, Struct. Chem., 2004, 15, 327.

    Article  Google Scholar 

  11. F. A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, 2nd ed., J. Wiley and Sons, New York, 1966.

    Google Scholar 

  12. J. Garcia-Lozano, J. Server-Carrio, E. Coret, J.-V. Folgado, E. Escrivia, and R. Ballesteros, Inorg. Chim. Acta, 1996, 75, 245.

    Google Scholar 

  13. S. B. Sanni, H. J. Behm, P. T. Beurskens, G. A. van Albada, J. Reedijk, A. T. H. Lenstra, A. W. Addison, and M. Palaniandavar, J. Chem. Soc., Dalton Trans., 1988, 1429.

  14. G. Bernardinelli, G. Hopfgartner, and A. F. Williams, Acta Cristallogr., Sect. C, 1990, 46, 1642.

    Article  Google Scholar 

  15. Organic Electrochemistry, Ed. M. M. Baiser, Marcel Dekker, New York, 1983.

    Google Scholar 

  16. S. Roffia and G. Feroci, Electroanal. Chem., 1978, 88, 169.

    Article  CAS  Google Scholar 

  17. Ch. Mann and K. Barnes, Electrochemical Reactions in Nonaqueous Systems, Marcel Dekker, New York, 1967.

    Google Scholar 

  18. R. Woods, G. A. Hope, and K. Watlong, J. Appl. Electrochem., 2000, 30, 1209.

    Article  CAS  Google Scholar 

  19. R. W. Hay, J. A. Crayston, T. J. Cromie, P. Lightfoot, and D. C. L. de Alwis, Polyhedron, 1997, 16, 3557.

    Article  CAS  Google Scholar 

  20. A. M. Bond, Modern Polarographic Methods in Analytical Chemistry, Marcell Dekker, New York, 1980.

    Google Scholar 

  21. K. P. Butin, A. A. Moiseeva, E. K. Beloglazkina, Yu. B. Chudinov, A. A. Chizhevskii, A. V. Mironov, B. N. Tarasevich, A. V. Lalov, and N. V. Zyk, Izv. Akad. Nauk, Ser. Khim., 2005, 169 [Russ. Chem. Bull., Int. Ed., 2005, 54, 173].

    Google Scholar 

  22. J. Musie, J. H. Reibenspies, and M. Y. Darsenbourg, Inorg. Chem., 1998, 37, 302.

    Article  CAS  Google Scholar 

  23. G. H. Brown and R. Al-Urfali, J. Am. Chem. Soc., 1958, 80, 2111.

    Article  Google Scholar 

  24. D. L. McMasters, R. B. Dunlap, J. R. Kuempel, L. W. Kreider, and T. R. Shearer, Anal. Chem., 1967, 39, 103.

    Article  CAS  Google Scholar 

  25. J. J. P. Stewart, J. Comput. Chem., 1989, 10, 209.

    Article  CAS  Google Scholar 

  26. Enraf-Nonius. CAD-4 Software. Version 5.0, Enraf-Nonius, Delft (The Netherlands), 1989.

  27. L. J. Farrugia, J. Appl. Crystallogr., 1999, 32, 837.

    Article  Google Scholar 

  28. A. C. T. North, D. C. Phillips, and F. S. Mathews, Acta Crystallogr., Sect. A, 1968, 24, 351.

    Article  Google Scholar 

  29. P. T. Beurskens, G. Beurskens, W. P. Bosman, R. de Gelder, S. Garcia-Granda, R. O. Gould, R. Israel, and J. M. M. Smits, The DIRDIF-96 Program System. Technical Report, Crystallography Laboratory, University of Nijmegen (The Netherlands), 1996.

    Google Scholar 

  30. G. M. Sheldrick, SHELXL-97, Program for the Refinement of Crystal Structures, University of Göttingen, Göttingen (Germany), 1997.

    Google Scholar 

  31. H. D. Flack, Acta Crystallogr., Sect. A, 1983, 39, 876.

    Article  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, M. V. Lomonosov Moscow State University, 1 Leninskie Gory, 119992, Moscow, Russian Federation

    E. K. Beloglazkina, I. V. Yudin, A. G. Majouga, A. A. Moiseeva, A. I. Tursina & N. V. Zyk

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  1. E. K. Beloglazkina
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  2. I. V. Yudin
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  3. A. G. Majouga
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  4. A. A. Moiseeva
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  5. A. I. Tursina
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1738–1744, October, 2006.

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Beloglazkina, E.K., Yudin, I.V., Majouga, A.G. et al. Synthesis and electrochemical study of 2-(2-pyridyl)benzothiazole complexes with transition metals (CoII, NiII, and CuII). Molecular structure of aquabis[2-(2-pyridyl)benzothiazole]copper(II) diperchlorate. Russ Chem Bull 55, 1803–1809 (2006). https://doi.org/10.1007/s11172-006-0490-x

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  • DOI: https://doi.org/10.1007/s11172-006-0490-x

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