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Dynamic NMR spectroscopy in studies of the kinetics of photoinduced chemical exchange in solutions

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Abstract

Modern NMR-based methods of studying the kinetics and mechanisms of reversible photochemical reactions in solutions are surveyed. Detailed consideration of peculiar features of the experimental techniques based on NMR lineshape analysis and double resonance NMR and used for the determination of the effective rate constants for and quantum yields of photoinduced chemical exchange processes is presented.

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  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrent’eva, 630090, Novosibirsk, Russian Federation

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1631–1641, October, 2006.

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Babailov, S.P. Dynamic NMR spectroscopy in studies of the kinetics of photoinduced chemical exchange in solutions. Russ Chem Bull 55, 1691–1702 (2006). https://doi.org/10.1007/s11172-006-0476-8

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