Abstract
The electrochemical behavior of a series of halogen-containing cyclohexa-2,5-dien-1-ones at the glassy-carbon electrode in DMF was studied. The reductive dehalogenation of 2-bromo-5-dibromomethyl-4-dichloromethyl-4-methylcyclohexa-2,5-dien-1-one first results in the elimination of the carbonylallylic bromine atoms, then the carbonylic bromine atom is elimi-nated, and finally, the neopentylic chlorine atoms are eliminated.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1558–1564, September, 2006.
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Gavrilova, G.V., Moiseeva, A.A., Beloglazkina, E.K. et al. Electrochemical study of the sequence of reductive dehalogenation of 2-bromo-5-dibromomethyl-4-dichloromethyl-4-methylcyclohexa-2,5-dien-1-one and its analogs. Russ Chem Bull 55, 1617–1623 (2006). https://doi.org/10.1007/s11172-006-0463-0
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DOI: https://doi.org/10.1007/s11172-006-0463-0