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Stacking reactions of the borole complex Cp*Rh(η5-C4H4BPh) with the dicationic fragments [Cp*M]2+ (M = Rh or Ir)

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Abstract

The reaction of the (borole)rhodium iodide complex [(η-C4H4BPh)RhI]4 with Cp*Li afforded the sandwich compound Cp*Rh(η-C4H4BPh) (4). The reactions of compound 4 with the solvated complexes [Cp*M(MeNO2)3]2+(BF −4 )2 gave triple-decker cationic complexes with the central borole ligand [Cp*Rh(η-η5:η5-C4H4BPh)MCp*]2+(BF −4 )2 (M = Rh (5) or Ir (7)). The structure of complex 4 was established by X-ray diffraction.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    D. A. Loginov, D. V. Muratov, Z. A. Starikova, P. V. Petrovskii & A. R. Kudinov

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  1. D. A. Loginov
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  2. D. V. Muratov
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  3. Z. A. Starikova
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  4. P. V. Petrovskii
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  5. A. R. Kudinov
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1525–1527, September, 2006.

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Loginov, D.A., Muratov, D.V., Starikova, Z.A. et al. Stacking reactions of the borole complex Cp*Rh(η5-C4H4BPh) with the dicationic fragments [Cp*M]2+ (M = Rh or Ir). Russ Chem Bull 55, 1581–1584 (2006). https://doi.org/10.1007/s11172-006-0457-y

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  • DOI: https://doi.org/10.1007/s11172-006-0457-y

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