Abstract
1-Hydrosilatrane reduces AgNO3 and CuCl2 in CH3CN to form metallic silver and CuCl, respectively; other reaction products are the silatranyl nitrate O2NOSi(OCH2CH2)3N and the 1-chlorosilatrane ClSi(OCH2CH2)3N.
Similar content being viewed by others
References
M. T. Attar-Bashi, C. Eaborn, J. Vencl, and D. R. M. Walton, J. Organomet. Chem., 1976, 117, C87.
C. Chuit, R. J. P. Corriu, R. Perz, and C. Reys, Synthesis, 1982, 981; M. Kira, K. Sato, and H. Sakurai, Chem. Lett., 1987, 2243; M. Fujita and H. Hiyama, Tetrahedron Lett., 1987, 2263; T. M. Onaka, K. Higuchi, H. Nanami, Y. Izumi, and Y. Bull, Chem. Soc. Jpn, 1993, 66, 2638; R. Radinov and E. S. Schnurman, Tetrahedron Lett., 1999, 40, 243; J. F. Reichwein, S. T. Lacono, and B. L. Pagenkopf, Tetrahedron, 2002, 58, 3813.
M. G. Voronkov and M. S. Sorokin, Zh. Obshch. Khim., 1986, 56, 1098 [J. Gen. Chem. USSR, 1986, 56 (Engl. Transl.)].
G. Cerveau, C. Chuit, E. Colomer, R. J. P. Corriu, and C. Reys, Organometallics, 1990, 9, 2415.
I. S. Birgele, A. A. Kemme, E. L. Kupche, I. B. Mazheika, and V. D. Shatts, Kremniiorganicheskie proizvodnye aminospirtov [Organosilicon Derivatives of Amino Alcohols], Ed. E. Ya. Lukevics, Zinatne, Riga, 1987, 230 pp. (in Russian).
E. Lukevics, L. Ignatovich, L. Golomba, Ju. Popelis, and S. Belyakov, Main Group Metal Chem., 2000, 23, 761.
L. Bellamy, Advances in Infrared Group Frequencies, Methuen and Co. LTD, Bungay, Suffolk, 1968.
V. A. Pestunovich, Yu. Yu. Popelis, E. Ya. Lukevics, and M. G. Voronkov, Izv. Akad. Nauk Latv. SSR, Ser. Khim. [Bull. Acad. Sci. Latv. SSR, Div. Chem. Sci.], 1973, 365 (in Russian).
A. R. Cherkasov, V. I. Galkin, and R. A. Cherkasov, Usp. Khim., 1996, 65, 695 [Russ. Chem. Rev., 1996, 65 (Engl. Transl.)].
S. R. Bahr and P. Boudjouk, J. Am. Chem. Soc., 1993, 115, 4514.
M. G. Voronkov, V. P. Baryshok, L. P. Petukhov, V. I. Rakhlin, R. G. Mirskov, and V. A. Pestunovich, J. Organomet. Chem., 1988, 358, 39.
G. I. Zelchan and M. G. Voronkov, Khim. Geterotsikl. Soedin., 1967, 371 [Chem. Heterocycl. Compd., 1967 (Engl. Transl.)].
A. J. Gordon and R. A. Ford, The Chemist’s Companion. A Handbook of Practical Data, Techniques and References, John Wiley and Sons, New York, 1972.
Author information
Authors and Affiliations
Additional information
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 725–726, April, 2006.
Rights and permissions
About this article
Cite this article
Lazareva, N.F., Pestunovich, V.A. Reactions of 1-hydro-and 1-halosilatranes with metal salts. Russ Chem Bull 55, 751–752 (2006). https://doi.org/10.1007/s11172-006-0326-8
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/s11172-006-0326-8