Abstract
The hydrolysis of 1,2-dichlorotetramethyldisilane was studied at different temperatures. At reduced temperatures, the hydrolysis gave permethylcyclo(oxadisilanes) [(Me2Si)2O]n (n = 2 and 3) and α,ω-dihydroxypermethyloligo(oxadisilanes) HO[(SiMe2)2O]mH (m = 1–5). The formation of the latter was proved by the GC-MS method.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 722–724, April, 2006.
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Chernyavskii, A.I., Pleshkova, A.P. Effect of the temperature on the composition and ratio of hydrolysis products of 1,2-dichlorotetramethyldisilane. Russ Chem Bull 55, 748–750 (2006). https://doi.org/10.1007/s11172-006-0325-9
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DOI: https://doi.org/10.1007/s11172-006-0325-9