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Volume properties of solutions of oleic, linoleic, and linolenic acids in n-hexane and n-heptane at 298.15 K

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Abstract

Densities of solutions of oleic, linoleic, and linolenic acids in n-hexane and n-heptane were measured using a vibrating-tube densimeter at 298.15 K in a concentration range of 0–0.012 molar fractions of solute. The measurement error does not exceed ±5·10−6 g cm−3. The limiting partial molar volumes of fatty acids of the studied series in n-hexane and n-heptane and the excess volume properties of binary mixtures were calculated. On going from oleic to linolenic acid, the number of double bonds (>C=C<) in a solute molecule increases, the hydrocarbon chain length in a solvent molecule decreases, and compactness of the structure packing of the resulting solution increases. This is caused, as a whole, by the enhancement of the n-alkane—acid intermolecular interaction.

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Authors and Affiliations

  1. Institute of Solution Chemistry, Russian Academy of Sciences, 1 ul. Akademicheskaya, 153045, Ivanovo, Russian Federation

    A. G. Ramazanova, V. I. Yashkova, O. V. Balmasova, V. V. Korolev & E. V. Ivanov

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  1. A. G. Ramazanova
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  2. V. I. Yashkova
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  3. O. V. Balmasova
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  4. V. V. Korolev
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  5. E. V. Ivanov
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 643–647, April, 2006.

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Ramazanova, A.G., Yashkova, V.I., Balmasova, O.V. et al. Volume properties of solutions of oleic, linoleic, and linolenic acids in n-hexane and n-heptane at 298.15 K. Russ Chem Bull 55, 666–671 (2006). https://doi.org/10.1007/s11172-006-0310-3

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  • DOI: https://doi.org/10.1007/s11172-006-0310-3

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