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Formation of palladium nanoparticles in olefin oxidation with iron(III) aqua ions in the presence of the Pd/ZrO2/SO4 metallic catalyst

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Abstract

The reactions of the Pd/ZrO2/SO4-catalyzed oxidation of ethylene, propene, and but-1-ene in a 0.1–1.5 M solution of perchloric acid with iron(III) aqua ions to carbonyl compounds, viz., acetaldehyde, acetone, and methyl ethyl ketone, respectively, were studied. The formation of palladium nanoparticles (5 nm) in solution on contact of the initial heterogeneous Pd/ZrO2/SO4 catalyst with perchloric acid was proved by transmission electron microscopy. The palladium nanoparticles are assumed to play the key role in olefin oxidation with the iron(III) aqua ions.

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Authors and Affiliations

  1. St. Petersburg State Technological Institute (Technical University), 26 Moskovsky prosp., 198013, St. Petersburg, Russian Federation

    V. V. Potekhin & V. A. Matsura

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  1. V. V. Potekhin
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  2. V. A. Matsura
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 627–632, April, 2006.

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Potekhin, V.V., Matsura, V.A. Formation of palladium nanoparticles in olefin oxidation with iron(III) aqua ions in the presence of the Pd/ZrO2/SO4 metallic catalyst. Russ Chem Bull 55, 650–655 (2006). https://doi.org/10.1007/s11172-006-0307-y

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  • DOI: https://doi.org/10.1007/s11172-006-0307-y

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