Abstract
The results of experimental research into structuration of associated pure liquids and electrolyte solutions in these liquids by NMR spectroscopy are summarized. The influence of self-organization on the rate and relay mechanism of proton mobility, chemical kinetics, and thermodynamics is analyzed.
Similar content being viewed by others
References
M. Tuckerman, K. Laasonen, M. Sprik, and M. Parrinello, J. Phys. Chem., 1995, 99, 5749; M. Tuckerman, K. Laasonen, M. Sprik, and M. Parrinello, J. Chem. Phys., 1995, 103, 150.
N. Agmon, Chem. Phys. Lett., 1995, 244, 456.
N. Agmon, J. Chim. Phys., 1996, 93, 1714.
M. Pavese, S. Chawla, D. S. Lu, J. Lobaugh, and G. A. Voth, J. Chem. Phys., 1997, 107, 7428.
R. Vuilleumier and D. Borgis, J. Mol. Struct., 1997, 437, 555; R. Vuilleumier and D. Borgis, 1998, Chem. Phys. Lett., 284, 71.
M. Pavese and G. A. Voth, Ber. Bunsen. Phys. Chem., 1998, 102, 527.
N. Agmon, Israel J. Chem., 1999, 39, 493.
D. Marx, M. E. Tuckerman, J. Hutter, and M. Parrinello, Nature, 1999, 397, 601.
J. T. Hynes, Nature, 1999, 397, 565.
K. D. Kreuer, Chem. Mater., 1996, 8, 610; A. B. Yaroslavtsev and V. Yu. Kotov, Izv. Akad. Nauk, Ser. Khim., 2002, 515 [Russ. Chem. Bull., Int. Ed., 2002, 51, 555].
N. G. Yunda, G. V. Lagodzinskaya, and G. B. Manelis, Izv. Akad. Nauk SSSR, Ser. Khim., 1975, 2443 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1975, 24, 2330 (Engl. Transl.)].
N. G. Yunda, G. V. Lagodzinskaya, E. B. Fel’dman, and G. B. Manelis, Izv. Akad. Nauk SSSR, Ser. Khim., 1977, 1285 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1977, 26, 1181 (Engl. Transl.)].
G. V. Lagodzinskaya, N. G. Yunda, and G. B. Manelis, Izv. Akad. Nauk SSSR, Ser. Khim., 1980, 778 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1980, 29, 532 (Engl. Transl.)].
G. V. Lagodzinskaya, N. G. Yunda, and G. B. Manelis, Izv. Akad. Nauk SSSR, Ser. Khim., 1980, 987 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1980, 29, 695 (Engl. Transl.)].
G. V. Lagodzinskaya, N. G. Yunda, and G. B. Manelis, Izv. Akad. Nauk SSSR, Ser. Khim., 1981, 953 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1981, 30, 724 (Engl. Transl.)].
N. G. Yunda, G. V. Lagodzinskaya, and G. B. Manelis, Izv. Akad. Nauk SSSR, Ser. Khim., 1972, 1284 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1972, 21 (Engl. Transl.)].
N. G. Yunda, Ph. D. (Chem.) Thesis, Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, 1992 143 pp. (in Russian).
G. V. Lagodzinskaya, N. G. Yunda, and G. B. Manelis, Chem. Phys., 2002, 282, 51.
G. Zundel and J. Fritsch, in The Chemical Physics of Solvation, Eds R. R. Dogonadze, E. Kalman, A. A. Kornyshev, and J. Ulstrup, Elsevier, Amsterdam, 1986, 2, 21.
B. Brzezinski and G. Zundel, J. Chem. Soc., Faraday Trans. 2, 1979, 75, 661.
H.-P. Cheng, Phys. Chem. A, 1998, 102, 6201.
D. R. Clutter and T. J. Swift, J. Am. Chem. Soc., 1968, 90, 601.
P. W. Atkins, A. Loewenstein, and Y. Margalit, Mol. Phys., 1969, 17, 329.
J. D. Halliday, P. E. Binder, and S. Padamshi, Can. J. Chem., 1984, 62, 1258.
F. Huisken and T. Pertsch, Chem. Phys., 1988, 126, 213.
D. Gerritzen and H. H. Limbach, Ber. Bunsen-Ges. Phys. Chem., 1981, 85, 527.
V. A. Daragan, A. U. Stepanyants, and T. N. Khazanovich, Zh. Strukt. Khim., 1978, 19, 474 [J. Struct. Chem. USSR, 1978, 19 (Engl. Transl.)].
W. A. P. Luck, Acta Chim. Hung., 1986, 121, 119.
H. G. Hertz, in Progress in Nuclear Magnetic Resonance Spectroscopy, Eds J. W. Emsley, F. Feeney, and L. H. Sutcliffe, Pergamon Press, Oxford-London, 1967, 3, 159.
A. Loewenstein and A. Szoke, J. Am. Chem. Soc., 1962, 84, 1151.
L. Pauling, The Nature of Hydrogen Bond, Oxford University Press, Ithaca-New York, 1960.
W. L. Jorgensen, J. Am. Chem. Soc., 1980, 102, 543.
S. Sarkar, A. K. Karmakar, and R. N. Joarder, J. Phys. Chem. A, 1997, 101, 3702.
Y. Kamishina, J. Magn. Res., 1975, 20, 388.
R. L. Collin and W. N. Lipscomb, Acta Crystallogr., 1951, 4, 10.
B. G. Rao and U. C. Singh, J. Am. Chem. Soc., 1991, 113, 4381.
J. Pople, W. Schneider, and H. Bernstein, High-Resolution Nuclear Magnetic Resonance, McGraw-Hill, New York, 1959.
M. Saunders and J. Hune, J. Chem. Phys., 1958, 29, 1319.
J. C. Hindman, J. Chem. Phys., 1966, 44, 4582.
S. E. Odinokov, A. A. Mashkovskii, and A. K. Dzizenko, Dokl. Akad. Nauk SSSR, 1975, 220, 1130 [Dokl. Chem., 1975 (Engl. Transl.)].
H. C. Chang, J. C. Jiang, S. H. Lin, Y. T. Lee, and H. C. Chang, J. Phys. Chem. A, 1999, 103, 2941.
M. T. Coolbaugh and J. F. Garvey, Chem. Soc. Rev., 1992, 163.
G. V. Lagodzinskaya, I. Yu. Kozyreva, N. G. Yunda, and G. B. Manelis, Izv. Akad. Nauk SSSR, Ser. Khim., 1984, 2212 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1984, 33, 2017 (Engl. Transl.)].
N. M. Emanuel’ and D. G. Knorre, Kurs khimicheskoi kinetiki [Handbook of Chemical Kinetics], Vysshaya shkola, Moscow, 1969, 432 pp. (in Russian).
V. I. Chizhik, Dr. Sc. (Chem.) Thesis, Leningrad State University, Leningrad, 1981, 46 pp. (in Russian).
P. A. Zagorets, V. I. Ermakov, and A. P. Grunau, Zh. Fiz. Khim., 1965, 39, 9 [J. Phys. Chem. USSR, 1965, 39 (Engl. Transl.)].
Yu. S. Bogachev and N. N. Shapet’’ko, Zh. Fiz. Khim., 1988, 62, 2617 [J. Phys. Chem. USSR, 1988, 62 (Engl. Transl.)].
G. V. Lagodzinskaya, N. G. Yunda, E. P. Kirpichev, A. I. Kazakov, Yu. I. Rubtsov, V. O. Zavel’skii, and G. B. Manelis, Khim. Fiz., 1989, 236 [Chem. Phys. USSR, 1989 (Engl. Transl.)].
G. V. Lagodzinskaya, M. V. Loginova, N. G. Yunda, V. O. Zavel’skii, and G. B. Manelis, Koord. Khim., 1998, 24, 152 [Russ. J. Coord. Chem., 1998, 24 (Engl. Transl.)].
V. I. Ermakov, V. V. Shcherbakov, and S. B. Khubetsov, Zh. Fiz. Khim., 1973, 47, 728 [J. Phys. Chem. USSR, 1973, 47 (Engl. Transl.)].
J. Burgess, Ions in Solution: Basic Principles of Chemical Interaction, Halsted Press, Chichester, 1988.
H. Ohtaki and T. Radnai, Chem. Rev., 1993, 93, 1157.
G. V. Lagodzinskaya, G. B. Manelis, Z. K. Nikitina, V. I. Shestov, and V. Ya. Rosolovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 1985, 781 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1985, 34, 708 (Engl. Transl.)].
R. W. J. Duerst, Chem. Phys., 1968, 48, 2275.
Yu. V. Karyakin and N. N. Angelov, Chistye khimicheskie veshchestva [Pure Chemical Substances], Khimiya, Moscow, 1974, 407 pp. (in Russian).
F. Daniels and F. Bright, J. Am. Chem. Soc., 1921, 43, 53.
K. V. Titova, E. P. Kirpichev, and V. Ya. Rosolovskii, Tez. dokl., IX Vsesoyuzn. konf. “Kalorimetriya i khimicheskaya termodinamika” [Abstrs. of Papers, IX All-Union Conf. “Calorimetry and Chemical Thermodynamics”], Tbilisi, 1982, 20 (in Russian).
I. Yu. Kozyreva, G. V. Lagodzinskaya, Z. B. Maiofis, and E. B. Fel’dman, Teoret. Eksp. Khim., 1984, 20, 452 [Theor. Exp. Chem., 1084, 20 (Engl. Transl.)].
G. V. Lagodzinskaya and I. Yu. Klimenko, J. Magn. Res., 1982, 49, 1.
V. Ya. Rosolovskii, Khimiya bezvodnoi khlornoi kisloty [Chemistry of Anhydrous Perchloric Acid], Nauka, Moscow, 1966, 140 pp. (in Russian).
O. Ya. Samoilov, Sostoyanie i rol”vody v biologicheskikh ob"ektakh [State and Role of Water in Biological Materials], Nauka, Moscow, 1967, 31 pp. (in Russian).
N. B. Librovich, V. P. Sakun, and N. D. Sokolov, in Vodorodnaya svyaz [Hydrogen Bond], Nauka, Moscow, 1981, 174 pp. (in Russian).
D. Eizenberg and V. Kautsman, Struktura i svoistva vody [Structure and Properties of Water], Gidrometeoizdat, Leningrad, 1975, 280 pp. (in Russian).
C. C. Addison, Chem. Rev., 1980, 80, 21.
S. S. Odokienko, N. V. Latypov, I. N. Shokhor, Yu. A. Fedorov, and E. N. Vishnevskii, Zh. Prikl. Khim., 1978, 51, 683 [J. Appl. Chem. USSR, 1978, 51 (Engl. Transl.)].
C. C. Addison and N. Logan, in Developments in Inorganic Nitrogen Chemie, Ed. C. B. Colburn, Elsevier, Amsterdam, 1973, 2, 27. z
B. V. Nekrasov, Osnovy obshchei khimii [Fundamentals of General Chemistry], Khimiya, Moscow, 1973, 1, 428 pp. (in Russian).
E. Berl and H. H. Saenger, Monatsh. Chem., 1929, 54, 1036.
A. G. Udovenko, V. A. Granzhan, and D. N. Bugun, Vyazkost’ i poverkhnostnoe natyazhenie rastvorov v N 2O4 i N 2O5 azotnoi kislote [Viscosity and Surface Tension of N 2O4 and N 2O5 Solutions in Nitric Acid], Leningrad, 1983, 5 pp.; Deposited in VINITI, 29.03.83, No. 1553-83 (in Russian).
G. M. Kurbatov and I. I. Skorokhodov, Zh. Neorg. Khim., 1976, 21, 2576 [J. Inorg. Chem. USSR, 1976, 21 (Engl. Transl.)].
G. M. Shutov, O. G. Ul’ko, L. M. Efremova, and E. Yu. Orlova, Kinetika i mekhanizm termicheskogo razlozheniya rastvorov N 2O5 v azotnoi kislote i rastvorov HNO 3 v sernoi kislote [Kinetics and Mechanism of Thermal Decomposition of N 2O5 Solutions in Nitric Acid and of HNO 3 Solutions in Sulfuric Acid], Moscow, 1982, 7 pp.; Deposited in VINITI 07.04.82, No. 2350-82 (in Russian).
O. P. Yablonskii, Zh. Fiz. Khim., 1975, 49, 2538 [J. Phys. Chem. USSR, 1975, 49 (Engl. Transl.)].
J.-P. Kintzinger, in Nuclear Magnetic Resonance. Basic Principles and Progress, Eds P. Diehl, E. Fluck, and R. Kosfield, Springer, Berlin, 1981, 17, 1.
M. A. Anisimov, Kriticheskie yavleniya v zhidkostyakh i zhidkikh kristallakh [Critical Phenomena in Liquids and Liquid Crystals], Nauka, Moscow, 1987 (in Russian).
K. P. Mishchenko and G. M. Poltoratskii, Voprosy termodinamiki i stroeniya vodnykh i nevodnykh rastvorov elektrolitov [Problems of Thermodynamics and Structures of Aqueous and Nonaqueous Electrolyte Solutions], Khimiya, Leningrad, 1968, 352 pp. (in Russian).
G. Zundel, in Trends in Physical Chemistry, Ed. J. Menon, Research Trends, Trivandrum, 1992, 2, 129.
A. C. Mitus and A. Z. Patashinskii, Phys. Lett., 1985, 113A, 41.
H. J. Van Wyk, Z. anorg. und allg. Chem., B, 1906, 48, 1.
Yu. I. Rubtsov, G. B. Manelis, Z. I. Grigorovich, and V. Ya. Rosolovskii, Zh. Fiz. Khim., 1974, 48, 1399 [J. Phys. Chem. USSR, 1974, 48 (Engl. Transl.)].
Z. K. Nikitina and V. Ya. Rosolovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 1977, 1466 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1977, 26 (Engl. Transl.)].
A. I. Karelin, Z. I. Grigorovich, and V. Ya. Rosolovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 1975, 665 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1975, 24 (Engl. Transl.)].
N. S. Golubev, Khim. Fiz., 1983, 42 [Chem. Phys. USSR, 1983 (Engl. Transl.)].
E. S. Swinbourne, J. Chem. Soc., 1960, 2371.
J.-M. Lehn, Concepts and Perspectives: A Personal Account, Wiley VCH, Paperback, 1995.
J.-M. Lehn, Proc. Natl. Acad. Sci. USA, 2002, 99, 4763.
J.-M. Lehn, J. Coord. Chem., 1992, 27, 3.
V. A. Durov, J. Mol. Liquids, 2005, 118, 101.
M. G. Kiselev, Dr. Sc. (Chem.) Thesis, Institute of Solution Chemistry of the Russian Academy of Sciences, Ivanovo, 2003, 292 pp. (in Russian).
Author information
Authors and Affiliations
Additional information
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 577–601, April, 2006.
Rights and permissions
About this article
Cite this article
Lagodzinskaya, G.V., Yunda, N.G. & Manelis, G.B. Labile supramolecular structures and their dynamics in associated liquids based on NMR data. Russ Chem Bull 55, 597–623 (2006). https://doi.org/10.1007/s11172-006-0302-3
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/s11172-006-0302-3