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Synthesis of fluorine-containing tetraketones and diketo esters and luminescence-spectral properties of their complexes with lanthanide ions

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Abstract

The Claisen condensation of diesters of fluorinated dicarboxylic acids with 2-acetyl-naphthalene affords the corresponding naphthyl-containing tetraketones and diketo esters. The luminescence-spectral properties and stability constants of complexes of these compounds with Eu3+ ions were estimated. The characteristics of the complexes are comparable with those of fluorinated β-diketones containing chromophoric substituents, which are widely used in luminescence analysis. The synthesized naphthyl-containing diketo esters are efficiently conjugated with proteins and can be used for detection of biospecific interactions.

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Authors and Affiliations

  1. Military University of Radioactive, Chemical and Biological Defense, 13 Brigadirsky per., 105005, Moscow, Russian Federation

    D. V. Romanov & N. V. Vasil’ev

  2. State Scientific Center of the Russian Federation “State Research Institute of Biological Engineering,”, building 1, 75 Volokolamskoe shosse, 125424, Moscow, Russian Federation

    A. I. Lyamin, N. P. Ivanovskaya & N. S. Osinb

Authors
  1. D. V. Romanov
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  2. N. V. Vasil’ev
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  3. A. I. Lyamin
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  4. N. P. Ivanovskaya
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  5. N. S. Osinb
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Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 269—273, February, 2006.

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Romanov, D.V., Vasil’ev, N.V., Lyamin, A.I. et al. Synthesis of fluorine-containing tetraketones and diketo esters and luminescence-spectral properties of their complexes with lanthanide ions. Russ Chem Bull 55, 276–280 (2006). https://doi.org/10.1007/s11172-006-0248-5

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  • DOI: https://doi.org/10.1007/s11172-006-0248-5

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