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Interaction in fullerene—ammonia system at 423—773 K

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Abstract

The interaction of C60 fullerite and C60—NH4Cl mixture (8 wt. % of NH4Cl, promoter of reaction) with ammonia was investigated at a starting NH3 pressure of 0.6—0.7 MPa in the temperature range 423—773 K. Raising the temperature to 723 K is accompanied by hydrogenation and nitrogenation of the C60 matrix. Treatment of fullerite with ammonia at 773 K is followed by the decomposition of the fullerene framework and formation of X-ray amorphous product. The physico-chemical properties of hydride-nitride phases formed during the interaction were investigated.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    V. N. Fokin, Yu. M. Shul’ga, E. E. Fokina & B. P. Tarasov

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  1. V. N. Fokin
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  2. Yu. M. Shul’ga
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  3. E. E. Fokina
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  4. B. P. Tarasov
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 217—219, February, 2006.

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Fokin, V.N., Shul’ga, Y.M., Fokina, E.E. et al. Interaction in fullerene—ammonia system at 423—773 K. Russ Chem Bull 55, 222–224 (2006). https://doi.org/10.1007/s11172-006-0241-z

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  • DOI: https://doi.org/10.1007/s11172-006-0241-z

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