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Russian Chemical Bulletin

, Volume 55, Issue 1, pp 141–146 | Cite as

[6+4] Cycloaddition reactions of acceptor thiophene dioxides: The synthesis of substituted azulenes

  • A. M. Moiseev
  • E. S. Balenkova
  • V. G. Nenajdenko
Article

Abstract

[6+4] Cycloaddition reactions of functionalized thiophene dioxides with various fulvenes provided the corresponding azulenes. The observed regiochemistry was explained in terms of the HOMO—LUMO orbital coefficients.

Key words

[6+4] cycloaddition reactions azulenes regioselectivity acceptor thiophene 1,1-dioxides fulvenes 

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Copyright information

© Springer Science+Business Media, Inc. 2006

Authors and Affiliations

  • A. M. Moiseev
    • 1
  • E. S. Balenkova
    • 1
  • V. G. Nenajdenko
    • 1
  1. 1.Department of ChemistryM. V. Lomonosov Moscow State UniversityMoscowRussian Federation

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