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Ruthenium carborane complexes in the controlled radical polymerization of methyl methacrylate

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Abstract

New initiators based on closo-and exo-nido-ruthenacarboranes with phosphine and diphosphine ligands were proposed as chain growth regulators. They allow conducting the controlled synthesis of poly(methyl methacrylate) under radical initiation conditions.

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Authors and Affiliations

  1. Research Institute of Chemistry of the N. I. Lobachevsky Nizhnii Novgorod State University, 23, building 5, prosp. Gagarina, 603950, Nizhnii Novgorod, Russian Federation

    E. V. Kolyakina, I. D. Grishin & D. F. Grishin

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    D. N. Cheredilin, F. M. Dolgushin & I. T. Chizhevsky

Authors
  1. E. V. Kolyakina
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  2. I. D. Grishin
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  3. D. N. Cheredilin
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  4. F. M. Dolgushin
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  5. I. T. Chizhevsky
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  6. D. F. Grishin
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 85–89, January, 2006.

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Kolyakina, E.V., Grishin, I.D., Cheredilin, D.N. et al. Ruthenium carborane complexes in the controlled radical polymerization of methyl methacrylate. Russ Chem Bull 55, 89–93 (2006). https://doi.org/10.1007/s11172-006-0219-x

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  • DOI: https://doi.org/10.1007/s11172-006-0219-x

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