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Sandwich iridium complexes with the monoanionic carborane ligand [9-SMe2-7,8-C2B9H10]−

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Abstract

The reaction of the [(η-9-SMe2-7,8-C2B9H10)IrBr2]2 complex with Tl[Tl(η-7,8-C2B9H11)] afforded the iridacarborane compound (η-9-SMe2-7,8-C2B9H10)Ir(η-7,8-C2B9H11). The cationic complex [Cp*Ir(η-9-SMe2-7,8-C2B9H10)]+PF6 − (5 · PF6, Cp* is pentamethylcyclopentadienyl) was synthesized by the reaction of [Cp*IrCl2]2 with Na[9-SMe2-7,8-C2B9H10]. The structures of (η-9-SMe2-7,8-C2B9H10)Ir(η-cod) (cod is 1,5-cyclooctadiene) and 5 · PF6 were established by X-ray diffraction.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    D. A. Loginov, M. M. Vinogradov, D. S. Perekalin, Z. A. Starikova, K. A. Lyssenko, P. V. Petrovskii & A. R. Kudinov

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  1. D. A. Loginov
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  2. M. M. Vinogradov
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  3. D. S. Perekalin
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  4. Z. A. Starikova
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  5. K. A. Lyssenko
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  6. P. V. Petrovskii
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  7. A. R. Kudinov
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 81–84, January, 2006.

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Loginov, D.A., Vinogradov, M.M., Perekalin, D.S. et al. Sandwich iridium complexes with the monoanionic carborane ligand [9-SMe2-7,8-C2B9H10]− . Russ Chem Bull 55, 84–88 (2006). https://doi.org/10.1007/s11172-006-0218-y

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  • DOI: https://doi.org/10.1007/s11172-006-0218-y

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