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Reactions of germanium(II), tin(II), and antimony(III) chlorides with acenaphthene-1,2-diimines

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Abstract

Reactions of diimines dtb-BIAN and dph-BIAN with GeCl2 afford germanium(II) complexes with radical-anionic ligands, (dtb-BIAN)GeCl (5) and (dph-BIAN)GeCl (6a), respectively, where dtb-BIAN is 1,2-bis[(2,5-di-tert-butylphenyl)imino]acenaphthene and dph-BIAN is 1,2-bis[(2-biphenyl)imino]acenaphthene. The latter reaction gives 6a along with [(dph-BIAN)GeCl]+[GeCl3]− (6b). The reactions of tin(II) and antimony(III) chlorides with dtb-BIAN and dpp-BIAN produce complexes of these halides with neutral coordinated diimines, viz., (dtb-BIAN)SnCl2 (7) and (dpp-BIAN)SbCl3 (8) (dpp-BIAN is 1,2-bis[(2,6-di-isopropylphenyl)imino]acenaphthene). Paramagnetic complexes 5 and 6a were studied by ESR spectroscopy. Diamagnetic compounds 7 and 8 were characterized by 1H NMR spectroscopy. The structures of complexes 5, 6a,b, 7, 8, and (dpp-BIAN)Ge (9) were established by X-ray diffraction analysis.

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References

  1. D. Bourissou, O. Guerret, F. P. Gabbai, and G. Bertrand, Chem. Rev., 2000, 100, 39.

    Article  CAS  Google Scholar 

  2. N. J. Hill and R. West, J. Organomet. Chem., 2004, 689, 4165.

    Article  CAS  Google Scholar 

  3. O. Kühl, Coord. Chem. Rev., 2004, 248, 411.

    Article  Google Scholar 

  4. T. Gans-Eichler, D. Gudat, and M. Nieger, Angew. Chem., Int. Ed., 2002, 41, 1888.

    Article  CAS  Google Scholar 

  5. J. W. Sprengers, J. Wassenaar, N. D. Clement, K. J. Cavell, and C. J. Elsevier, Angew. Chem., Int. Ed., 2005, 44, 2026; (b) D. Kremzow, G. Seidel, C. W. Lehmann, and A. Fuerstner, Chem. Eur. J., 2005, 11, 1833; (c) I. Oezdemir, S. Demir, Y. Goek, E. Cetinkaya, and B. Cetinkaya, J. Mol. Cat., 2004, 222, 97; (d) A. O. Larsen, W. Leu, C. N. Oberhuber, J. E. Campbell, and A. H. Hoveyda, J. Am. Chem. Soc., 2004, 126, 11130; (e) U. L. Dharmasena, H. M. Foucault, E. N. dos Santos, D. E. Fogg, and S. P. Nolan, Organometallics, 2005, 24, 1056; (f) W. Stueer, B. Weberndoerfer, J. Wolf, and H. Werner, Dalton Trans., 2005, 10, 1796; (g) C. Slugovc, D. Burtscher, F. Stelzer, and K. Mereiter, Organometallics, 2005, 24, 2255; (h) P. E. Romero, W. E. Piers, and R. McDonald, Angew. Chem., Int. Ed., 2004, 43, 6161; (i) T. Ung, A. Hejl, R. H. Grubbs, and Y. Schrodi, Organometallics, 2004, 23, 5399; (j) R. Bujok, M. Bieniek, M. Masnyk, A. Michrowska, A. Sarosiek, H. Stepowska, D. Arlt, and K. Grela, J. Org. Chem., 2004, 69, 6894; (k) S. E. Lehman, Jr. and K. B. Wagener, Organometallics, 2005, 24, 1477; (l) J. S. Kingsbury and A. H. Hoveyda, J. Am. Chem. Soc., 2005, 127, 4510.

    Article  CAS  Google Scholar 

  6. V. Nair, S. Bindu, and V. Sreekumar, Angew. Chem., Int. Ed., 2004, 43, 5130; (b) K. Taichi, S. Kouji, and M. Keiji, Org. Lett., 2005, 7, 1347; (c) A. Chan and K. A. Scheidt, Org. Lett., 2005, 7, 905.

    Article  CAS  Google Scholar 

  7. B. Tumanskii, P. Pine, Y. Apeloig, N. J. Hill, and R. West, J. Am. Chem. Soc., 2004, 126, 7786; (b) W. J. Evans, J. M. Perotti, J. W. Ziller, D. F. Moser, and R. West, Organometallics, 2003, 22, 1160; (c) D. S. McGuinness, B. F. Yates, and K. J. Cavell, Organometallics, 2002, 21, 5408; (d) W. A. Herrmann, P. Harter, C. W. K. Gstottmayr, F. Bielert, N. Seeboth, and P. Sirsch, J. Organomet. Chem., 2002, 649, 141; (e) D. Amoroso, M. Haaf, G. P. A. Yap, R. West, and D. E. Fogg, Organometallics, 2002, 21, 534; (f) T. A. Schmedake, M. Haaf, B. J. Paradise, A. J. Millevolte, D. R. Powell, and R. West, J. Organomet. Chem., 2001, 636, 17; (g) H. P. Hratchian, T. Prendergast, and M. C. Milletti, Polyhedron, 2001, 20, 209; (h) J. M. Dysard and T. D. Tilley, Organometallics, 2000, 19, 4726; (i) T. A. Schmedake, M. Haaf, B. J. Paradise, D. Powell, and R. West, Organometallics, 2000, 19, 3263; (j) S. H. A. Petri, D. Eikenberg, B. Neumann, H.-G. Stammler, and P. Jutzi, Organometallics, 1999, 18, 2615; (k) M. Denk, R. K. Hayashi, and R. West, Chem. Commun., 1994, 33.

    Article  CAS  Google Scholar 

  8. P. Bazinet, G. P. A. Yap, and D. S. Richeson, J. Am. Chem. Soc., 2001, 123, 11162; (b) O. Kuhl, P. Lonnecke, and J. Heinicke, Inorg. Chem., 2003, 42, 2836.

    Google Scholar 

  9. L. A. Leites, S. S. Bukalov, A. V. Zabula, I. A. Garbuzova, D. F. Moser, and R. West, J. Am. Chem. Soc., 2004, 126, 4114.

    Article  CAS  Google Scholar 

  10. A. Naka, N. J. Hill, and R. West, Organometallics, 2004, 23, 6330.

    Article  CAS  Google Scholar 

  11. A. Dhiman, T. Mueller, R. West, and J. Becker, Organometallics, 2004, 23, 5689.

    Article  CAS  Google Scholar 

  12. I. L. Fedushkin, A. A. Skatova, V. A. Chudakova, G. K. Fukin, S. Dechert, and H. Schumann, Eur. J. Inorg. Chem., 2003, 3336; (b) I. L. Fedushkin, A. A. Skatova, V. K. Cherkasov, V. A. Chudakova, S. Dechert, M. Hummert, and H. Schumann, Chem. Eur. J., 2003, 9, 5778; (c) I. L. Fedushkin, A. A. Skatova, V. A. Chudakova, and G. K. Fukin, Angew. Chem., 2003, 115, 3416; Angew. Chem., Int. Ed., 2003, 42, 3294; (d) I. L. Fedushkin, N. M. Khvoinova, A. A. Skatova, and G. K. Fukin, Angew. Chem., Int. Ed., 2003, 42, 5223; (e) I. L. Fedushkin, V. A. Chudakova, G. K. Fukin, S. Dechert, M. Hummert, and H. Schumann, Izv. Akad. Nauk, Ser. Khim., 2004, 2634 [Russ. Chem. Bull., Int. Ed., 2004, 53, 2744]; (f) I. L. Fedushkin, A. A. Skatova, G. K. Fukin, M. Hummert, and H. Schumann, Eur. J. Inorg. Chem., 2005, 2332; (g) I. L. Fedushkin, A. A. Skatova, A. N. Lukoyanov, V. A. Chudakova, S. Dechert, M. Hummert, and H. Schumann, Izv. Akad. Nauk, Ser. Khim., 2004, 2641 [Russ. Chem. Bull., Int. Ed., 2004, 53, 2751]; (h) I. L. Fedushkin, A. A. Skatova, V. A. Chudakova, V. K. Cherkasov, G. K. Fukin, and M. A. Lopatin, Eur. J. Inorg. Chem., 2004, 388; (i) I. L. Fedushkin, V. A. Chudakova, A. A. Skatova, N. M. Khvoinova, Yu. A. Kurskii, T. A. Glukhova, G. K. Fukin, S. Dechert, M. Hummert, and H. Schumann, Z. Anorg. Allg. Chem., 2004, 630, 501; (j) I. L. Fedyushkin, A. A. Skatova, V. A. Chudakova, V. K. Cherkasov, S. Dechert, and H. Schumann, Izv. Akad. Nauk, Ser. Khim., 2004, 2051 [Russ. Chem. Bull., Int. Ed., 2004, 53, 2142]; (k) H. Schumann, M. Hummert, A. N. Lukoyanov, and I. L. Fedushkin, Organometallics, 2005, 24, 3891; (l) I. L. Fedushkin, A. A. Skatova, M. Hummert, and H. Schumann, Eur. J. Inorg. Chem., 2005, 1601; (m) I. L.Fedushkin, V. A. Chudakova, A. A. Skatova, and G. K. Fukin, Heteroatom Chem., 2005, 16, 663.

  13. I. L. Fedushkin, A. A. Skatova, V. A. Chudakova, N. M. Khvoinova, A. Yu. Baurin, S. Dechert, M. Hummert, and H. Schumann, Organometallics, 2004, 23, 3714; (b) I. L. Fedushkin, N. M. Khvoinova, A. Yu. Baurin, G. K. Fukin, V. K. Cherkasov, and M. P. Bubnov, Inorg. Chem., 2004, 43, 7807.

    Article  CAS  Google Scholar 

  14. G. A. Abakumov, V. K. Cherkasov, A. V. Piskunov, and N. O. Druzhkov, Dokl. Akad. Nauk, 2004, 399, 353 [Dokl. Chem., 2004, 399, 223]; (b) G. A. Abakumov, V. K. Cherkasov, A. V. Piskunov, I. A. Aivaz’yan, and N. O. Druzhkov, Dokl. Akad. Nauk, 2005, 404, 496 [Dokl. Chem., 2005, 404, 189].

    Google Scholar 

  15. M. K. Denk, K. Hatano, and A. J. Lough, Eur. J. Inorg. Chem., 1998, 1067; (b) D. F. Moser, T. Bosse, J. Olson, J. L. Moser, I. A. Guzei, and R. West, J. Am. Chem. Soc., 2002, 124, 4186; (c) A. Naka, N. J. Hill, and R. West, Organometallics, 2004, 23, 6330.

  16. G. M. Sheldrick, Empirical Absorption Correction Program, Universität Göttingen, Göttingen (Germany), 1996.

    Google Scholar 

  17. G. M. Sheldrick, Program for Crystal Structure Solution, Universität Göttingen, Göttingen (Germany), 1990.

    Google Scholar 

  18. G. M. Sheldrick, Program for Crystal Structure Refinement, Universität Göttingen, Göttingen (Germany), 1997.

    Google Scholar 

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Authors and Affiliations

  1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603950, Nizhny Novgorod, Russian Federation

    I. L. Fedushkin, N. M. Khvoinova, A. Yu. Baurin, V. A. Chudakova, A. A. Skatova, V. K. Cherkasov, G. K. Fukin & E. V. Baranov

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  1. I. L. Fedushkin
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  2. N. M. Khvoinova
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  3. A. Yu. Baurin
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  4. V. A. Chudakova
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  5. A. A. Skatova
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  6. V. K. Cherkasov
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  7. G. K. Fukin
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  8. E. V. Baranov
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 71–80, January, 2006.

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Fedushkin, I.L., Khvoinova, N.M., Baurin, A.Y. et al. Reactions of germanium(II), tin(II), and antimony(III) chlorides with acenaphthene-1,2-diimines. Russ Chem Bull 55, 74–83 (2006). https://doi.org/10.1007/s11172-006-0217-z

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  • DOI: https://doi.org/10.1007/s11172-006-0217-z

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