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Cage complexes as a molecular scaffold for polyfunctional and polytopic systems: Synthesis of the first closo-borate iron(II) clathrochelate

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Russian Chemical Bulletin Aims and scope

Abstract

The ribbed functionalization of the clathrochelate iron(II) tris-dioximates as a potential “molecular scaffold” for the synthesis of polyfunctional and polytopic complexes with closo-dodecaborate-anion substituents was performed. closo-Dodecaborate-substituted clathrochelate [FeBd2(Cl(B12H11NH)Gm)(BF)2]2− (where Bd2− is α-benzyldioxime dianion, Gm is glyoxime residue) dianion was prepared starting from dichloride clathrochelate FeBd2(Cl2Gm)(BF)2 precursor with amino-closo-dodecaborate (NBu4)[B12H11NH3] in the presence of potassium tert-amylate. This clathrochelate dianion was isolated as a tetra-n-butylammonium salt and characterized using elemental analysis, MALDI-TOF and PD mass, IR, UV-Vis, 57Fe Mössbauer spectra as well as by 1H, 11B and 13C{1H} NMR spectra.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    Ya. Z. Voloshin & Yu. N. Bubnov

  2. V. I. Vernadsky Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, 32/34 ul. Palladina, 03680, Kiev, Ukraine

    O. A. Varzatskii

  3. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    K. Yu. Zhizhin & N. T. Kuznetsov

Authors
  1. Ya. Z. Voloshin
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  2. O. A. Varzatskii
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  3. K. Yu. Zhizhin
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  4. N. T. Kuznetsov
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  5. Yu. N. Bubnov
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 21–24, January, 2006.

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Voloshin, Y.Z., Varzatskii, O.A., Zhizhin, K.Y. et al. Cage complexes as a molecular scaffold for polyfunctional and polytopic systems: Synthesis of the first closo-borate iron(II) clathrochelate. Russ Chem Bull 55, 22–25 (2006). https://doi.org/10.1007/s11172-006-0210-6

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  • DOI: https://doi.org/10.1007/s11172-006-0210-6

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