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Chemisorption of SO2 on the Zn-modified In2O3 surface

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Abstract

Chemisorption of SO2 and O2 on the In2O3 surface containing a zinc additive (0.4–2.7 at.%) was studied in a temperature range of 22–200 °C. At least three forms of sorbed SO2 exist on the modified In2O3 surface. The temperature affects the contribution of single forms of SO2 sorption and, hence, the change in the electric conductivity. The preliminary sorption of O2 favors the formation of a donor form of chemisorbed SO2.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    M. V. Vinokurova, L. E. Derlyukova & A. A. Vinokurov

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  1. M. V. Vinokurova
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  2. L. E. Derlyukova
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  3. A. A. Vinokurov
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2228–2232, October, 2005.

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Vinokurova, M.V., Derlyukova, L.E. & Vinokurov, A.A. Chemisorption of SO2 on the Zn-modified In2O3 surface. Russ Chem Bull 54, 2299–2304 (2005). https://doi.org/10.1007/s11172-006-0113-6

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  • DOI: https://doi.org/10.1007/s11172-006-0113-6

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