Abstract
Gold and nickel particles immobilized on alumina were prepared by the metal vapor synthesis and anionic adsorption methods. The dispersion of metals was determined by X-ray diffraction and transmission electron microscopy. The activity of nanoparticles, tested in model catalytic reactions of CCl4 addition to multiple bonds and allyl isomerization of allylbenzene, changes in a wide range (from 1 to 3000 (mole of product) (mole of Au)−1 h−1) and is parallel to the chromatographically measured heats of adsorption of the corresponding unsaturated substrates. The heat of adsorption of unsaturated hydrocarbons can serve as a criterion for the efficiency of the gold-containing catalyst in olefin conversion.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2215–2218, October, 2005.
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Smirnov, V.V., Lanin, S.N., Vasil’kov, A.Y. et al. Adsorption and catalytic conversion of hydrocarbons on nanosized gold particles immobilized on alumina. Russ Chem Bull 54, 2286–2289 (2005). https://doi.org/10.1007/s11172-006-0111-8
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DOI: https://doi.org/10.1007/s11172-006-0111-8