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Synthesis of carbon nanofibers by catalytic pyrolysis of ethylene and methane on hydrides of intermetallic compounds of lanthanum with nickel

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Abstract

Carbon nanofibers were synthesized by the pyrolysis of ethylene and methane on hydrides of intermetallides LaNinHx (n = 2, 3, 5; x = 0.1–4). The influence of parameters of the synthesis (temperature and the ratio of gases in an Ar: H2: C2H4 (CH4) mixture) on the structure of nanofibers thus formed was studied. Hydrides of nickel intermetallides are more efficient catalytic systems than metallic nickel.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    A. A. Volodin, P. V. Fursikov & B. P. Tarasov

  2. Institute of Problems of Microelectronic Technology and Ultrahigh-Purity Materials, Russian Academy of Sciences, 6 ul. Institutskaya, 142432, Chernogolovka, Moscow Region, Russian Federation

    Yu. A. Kasumov & I. I. Khodos

Authors
  1. A. A. Volodin
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  2. P. V. Fursikov
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  3. Yu. A. Kasumov
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  4. I. I. Khodos
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  5. B. P. Tarasov
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Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2210–2214, October, 2005.

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Volodin, A.A., Fursikov, P.V., Kasumov, Y.A. et al. Synthesis of carbon nanofibers by catalytic pyrolysis of ethylene and methane on hydrides of intermetallic compounds of lanthanum with nickel. Russ Chem Bull 54, 2281–2285 (2005). https://doi.org/10.1007/s11172-006-0110-9

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  • DOI: https://doi.org/10.1007/s11172-006-0110-9

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