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New antiferromagnetic tetranuclear pivalate complex containing FeIII and FeII atoms

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Abstract

The interaction of [K2FeIII 4(O)2(OOCCMe3)10(HOOCCMe3)2(H2O)2]n with 2-pyridinecarboxaldehyde results in a mixed-valence complex FeIIFeIII 3(μ3-O)2(μ2-OOCCMe3)7L2··2.5MeCN·3H2O (L = 2-NC5H4COOH0.75K0.25). The structure of the complex was established by X-ray analysis. The magnetic properties of the complex were studied.

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Author information

Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    M. A. Kiskin, A. A. Sidorov, G. G. Aleksandrov, V. M. Novotortsev, I. L. Eremenko & I. I. Moiseev

  2. International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation

    Yu. G. Shvedenkov & V. N. Ikorskii

Authors
  1. M. A. Kiskin
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  2. A. A. Sidorov
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  3. G. G. Aleksandrov
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  4. Yu. G. Shvedenkov
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  5. V. N. Ikorskii
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  6. V. M. Novotortsev
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  7. I. L. Eremenko
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  8. I. I. Moiseev
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Additional information

Dedicated to Academician A. L. Buchachenko on the occasion of his 70th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2145–2148, September, 2005.

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Kiskin, M.A., Sidorov, A.A., Aleksandrov, G.G. et al. New antiferromagnetic tetranuclear pivalate complex containing FeIII and FeII atoms. Russ Chem Bull 54, 2211–2214 (2005). https://doi.org/10.1007/s11172-006-0098-1

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  • DOI: https://doi.org/10.1007/s11172-006-0098-1

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