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Russian Chemical Bulletin

, Volume 54, Issue 9, pp 2182–2186 | Cite as

Reactions of acceptor thiophene 1,1-dioxides with dienes. Synthesis of bisadducts

  • V. G. Nenajdenko
  • A. M. Moiseev
  • E. S. Balenkova
Article

Abstract

Cycloaddition of dienes to thiophene dioxides affords mono-and bisadducts, depending on the reaction conditions. Regio-and stereochemical specific features of the cycloaddition were revealed. The thermal rearrangement of the monoadduct was found.

Key words

Diels-Alder reaction regioselectivity stereoselectivity acceptor thiophene 1,1-dioxides dienes dienophile bisadduct 

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Copyright information

© Springer Science+Business Media, Inc. 2005

Authors and Affiliations

  • V. G. Nenajdenko
    • 1
  • A. M. Moiseev
    • 1
  • E. S. Balenkova
    • 1
  1. 1.Department of ChemistryM. V. Lomonosov Moscow State UniversityMoscowRussian Federation

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