Abstract
Reactions of perfluoroalkyl-containing aliphatic 1,3-diketones with triethyl orthoformate afforded a number of β-ethoxy enones. Their reactions with o-phenylenediamine gave novel perfluoroalkyl-containing tridentate β-amino enones and tetradentate bis(β-amino enones) in high yields.
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Dedicated to Academician N. S. Zefirov on the occasion of his 70th birthday.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2086–2092, September, 2005.
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Mkrtchyan, E.G., Yachevskii, D.S., Chizhov, D.L. et al. Synthesis of perfluoroalkyl-containing tri-and tetradentate β-amino enones. Russ Chem Bull 54, 2150–2156 (2005). https://doi.org/10.1007/s11172-006-0090-9
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DOI: https://doi.org/10.1007/s11172-006-0090-9