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ESR investigation of paramagnetic derivatives of [6-tert-butyl-4-(5-tert-butyl-2-methyl-3,4-dioxocyclohexa-1,5-dien-1-yl)-3-methylcatecholato]triphenylantimony(V)

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Abstract

A number of paramagnetic derivatives of [6-tert-butyl-4-(5-tert-butyl-2-methyl-3,4-dioxocyclohexa-1,5-dien-1-yl)-3-methylcatecholato]triphenylantimony(v) were investigated by ESR spectroscopy. The reactions of this complex with Cp2Co or LiCl in the presence of Hgmetal. lead to the formation of free (nonchelated) radical anion semiquiones. Chelated complexes are formed in the case of Tl(Hg), Mn2(CO)10, Re2(CO)10, Sn2Ph6, Cu(met.), and CuCl + dppfc (dppfc is bis-diphenylphosphinoferrocene).

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References

  1. Molecular Electronics and Molecular Elecronic Devices, Ed. K. Sienik, CRC Press, Boca Raton, FL, 1994.

    Google Scholar 

  2. Molecular Electronics: Materials and Methods, Ed. P. I. Lazarev, Kluwer Academic Publishers, Dordrecht, The Netherlands, 1991.

    Google Scholar 

  3. O. Kahn and J. P. Launay, Chemtronics, 1988, 3, 140.

    Google Scholar 

  4. A. Caneschi, D. Gatteschi, and P. Rey, Prog. Inorg. Chem., 1993, 39, 331.

    Google Scholar 

  5. O. Kahn, Molecular Magnetism, VCH, New York, 1993.

    Google Scholar 

  6. V. I. Ovcharenko and R. Z. Sagdeev, Usp. Khim., 1999, 68 [Russ. Chem. Rev., 1999, 68, 345 (Engl. Transl.)].

  7. D. A. Shultz, Polyhedron, 2001, 20, 1627.

    Article  CAS  Google Scholar 

  8. D. A. Shultz, R. M. Fico, Jr., S. H. Bodnar, R. K. Kumar, K. E. Vostrikova, J. W. Kampf, and P. D. Boyle, J. Am. Chem. Soc., 2003, 125, 11761.

    Google Scholar 

  9. G. A. Abakumov, V. K. Cherkasov, V. I. Nevodchikov, V. A. Kuropatov, G. T. Yee, and C. G. Pierpont, Inorg. Chem., 2001, 40, 2434.

    Article  CAS  Google Scholar 

  10. G. A. Abakumov, V. K. Cherkasov, V. I. Nevodchikov, N. O. Druzhkov, and V. A. Kuropatov, Izv. Akad. Nauk. Ser. Khim., 1998, 904 [Russ. Chem. Bull., 1998, 47, 875 (Engl. Trans.)].

    Google Scholar 

  11. G. A. Abakumov, V. I. Nevodchikov, N. O. Druzhkov, L. N. Zakharov, L. G. Abakumova, Yu. A. Kurskii, and V. K. Cherkasov, Izv. Akad. Nauk. Ser. Khim., 1997, 804, [Russ. Chem. Bull., 1997, 771 (Engl. Trans.)].

  12. V. K. Cherkasov, E. V. Grunova, A. I. Poddel’sky, G. K. Fukin, Yu. A. Kurskii, L. G. Abakumova, and G. A. Abakumov, J. Organomet. Chem., 2005, 690, 1273.

    Article  CAS  Google Scholar 

  13. G. A. Abakumov, N. Yu. Kabarova, and V. K. Cherkasov, Metalloorgan. Khim., 1992, 5, 1145 [Organomet. Chem., 1992, 5 (Engl. Trans.)].

    CAS  Google Scholar 

  14. G. A. Abakumov, V. A. Muraev, and G. A. Razuvaev, Dokl. AN SSSR, 1974, 215, 1113 [Dokl. Chem., 1974 (Engl. Trans.)].

    CAS  Google Scholar 

  15. V. A. Muraev, G. A. Abakumov, and G. A. Razuvaev, Dokl. AN SSSR, 1974, 215, 159 [Dokl. Chem., 1974 (Engl. Trans.)].

    Google Scholar 

  16. B. A. Goodman and J. B. Raynor, Adv. Inorg. Chem. Radiochem., 1970, 13, 584.

    Google Scholar 

  17. G. A. Abakumov and V. A. Muraev, Dokl. Akad. Nauk SSSR, 1974, 217, 1313 [Dokl. Chem., 1974 (Engl. Trans.)].

    CAS  Google Scholar 

  18. A. I. Poddel’skii, G. A. Abakumov, M. P. Bubnov, V. K. Cherkasov, and L. G. Abakumova, Izv. Akad. Nauk. Ser. Khim., 2004, 1142 [Russ. Chem. Bull., Int. Ed., 2004, 53, 1189].

    Google Scholar 

  19. G. A. Razuvaev, V. K. Cherkasov, and G. A. Abakumov, J. Organomet. Chem., 1978, 690, 361.

    Google Scholar 

  20. G. A. Abakumov, V. K. Cherkasov, K. G. Shalnova, I. A. Teplova, and G. A. Razuvaev, J. Organomet. Chem., 1982, 236, 333.

    Article  CAS  Google Scholar 

  21. G. A. Abakumov, V. K. Cherkasov, A. V. Krashilina, I. L. Eremenko, and S. E. Nefedov, Izv. Akad. Nauk. Ser. Khim., 1998, 2333 [Russ. Chem. Bull., 1998, 47, 2262 (Engl. Trans.)].

    Google Scholar 

  22. G. A. Abakumov, A. V. Lobanov, V. K. Cherkasov, G. A. Razuvaev, Inorg. Chem. Acta, 1981, 49, 135.

    Article  CAS  Google Scholar 

  23. V. A. Muraev, V. K. Cherkasov, G. A. Abakumov, and G. A. Razuvaev, Dokl. Akad. Nauk SSSR, 1977, 236, 620 [Dokl. Chem., 1977 (Engl. Trans.)].

    CAS  Google Scholar 

  24. D. D. Perrin, W. L. F. Armarego, and D. R. Perrin, Purification of Laboratory Chemicals, Pergamon, Oxford, 1980.

    Google Scholar 

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Authors and Affiliations

  1. G. A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences, 49 ul. Tropinina, 603950, Nizhny Novgorod, Russian Federation

    V. K. Cherkasov, E. V. Grunova & G. A. Abakumov

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  1. V. K. Cherkasov
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  2. E. V. Grunova
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  3. G. A. Abakumov
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Dedicated to Academician A. L. Buchachenko on the occasion of his 70th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2004–2009, September, 2005.

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Cherkasov, V.K., Grunova, E.V. & Abakumov, G.A. ESR investigation of paramagnetic derivatives of [6-tert-butyl-4-(5-tert-butyl-2-methyl-3,4-dioxocyclohexa-1,5-dien-1-yl)-3-methylcatecholato]triphenylantimony(V). Russ Chem Bull 54, 2067–2072 (2005). https://doi.org/10.1007/s11172-006-0078-5

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  • DOI: https://doi.org/10.1007/s11172-006-0078-5

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