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Effect of H/D isotope substitution on polarizability of methanol molecules

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Abstract

The electron polarizabilities (α0·1024/cm3 molec.−1) were estimated from the data on refractive indices and molar volumes of H/D isotopomers of methanol at 25 °C using the Lorentz-Lorentz formula: 3.265 (CH3OH), 3.260 (CH3OD), 3.235 (CD3OH), and 3.231 (CD3OD). A relationship between the isotope effects for α0 and volume (packing) changes in the structure of liquid methanol induced by deuterosubstitution in the methanol molecule was proposed.

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Authors and Affiliations

  1. Institute of Chemistry of Solutions, Russian Academy of Sciences, 1 ul. Akademicheskaya, 153045, Ivanovo, Russian Federation

    E. V. Ivanov & V. K. Abrosimov

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  1. E. V. Ivanov
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  2. V. K. Abrosimov
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1927–1928, August, 2005.

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Ivanov, E.V., Abrosimov, V.K. Effect of H/D isotope substitution on polarizability of methanol molecules. Russ Chem Bull 54, 1987–1988 (2005). https://doi.org/10.1007/s11172-006-0069-6

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  • DOI: https://doi.org/10.1007/s11172-006-0069-6

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