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Ion-exchange selectivity of a network calixarene-containing polymer obtained by the template synthesis on Na+, K+, and Ba2+ matrices

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Abstract

The ion-exchange equilibrium in network polymers obtained from cis-2,8,14,20-tetraphenyl-4,6,10,12,16,18,22,24-octahydroxycalix[4]arene by template synthesis on cations Na+, K+, and Ba2+ as matrices was studied. The selectivity coefficients of ion exchanges Ba2+-H+, Na+-H+, K+-H+, Na+-K+, and Na+-NH4 + were determined. The template synthesis enhanced the affinity of the polymers to matrix-forming cations by 6–8 kJ mol−1.

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Authors and Affiliations

  1. Kemerovo Branch of the Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences, 18 Sovetskii prosp., 650099, Kemerovo, Russian Federation

    H. N. Altshuler, L. P. Abramova, N. V. Malyshenko, G. Yu. Shkurenko & E. V. Ostapova

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  1. H. N. Altshuler
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  2. L. P. Abramova
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  3. N. V. Malyshenko
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  4. G. Yu. Shkurenko
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  5. E. V. Ostapova
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1919–1922, August, 2005.

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Altshuler, H.N., Abramova, L.P., Malyshenko, N.V. et al. Ion-exchange selectivity of a network calixarene-containing polymer obtained by the template synthesis on Na+, K+, and Ba2+ matrices. Russ Chem Bull 54, 1978–1981 (2005). https://doi.org/10.1007/s11172-006-0067-8

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  • DOI: https://doi.org/10.1007/s11172-006-0067-8

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