Abstract
Stereoisomers of P—H-spirophosphorane were synthesized by the reaction of racemic (d,l)- and scalemic d- and l-hydrobenzoins with (MeO)3P or (Me2N)3P. A reversible interconversion of two possible diastereomeric forms of racemic spirophosphorane was observed.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1877–1880, August, 2005.
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Zheltukhin, V.F., Dovbysh, A.I., Sadkova, D.N. et al. Synthesis of stereoisomeric P—H-spirophosphoranes based on hydrobenzoin. Russ Chem Bull 54, 1935–1938 (2005). https://doi.org/10.1007/s11172-006-0060-2
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DOI: https://doi.org/10.1007/s11172-006-0060-2