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Reduction of AgI complexes with malonate ions in aqueous solution studied by pulse radiolysis

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Abstract

The formation of clusters CH2(COO−)(COOAg3 +) (absorption bands at 280 and 460 nm) by the reduction of silver ions in the presence of malonate ions in an aqueous solution was studied by pulse radiolysis. The disappearance of the clusters affords colloidal silver. The mechanism of silver nucleation was discussed, and the rate constants of some reactions were determined.

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Authors and Affiliations

  1. Institute of Physical Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    B. G. Ershov & A. V. Gordeeva

  2. Hahn-Meitner Institute, 14109, Berlin, Germany

    E. Janata

Authors
  1. B. G. Ershov
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  2. E. Janata
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  3. A. V. Gordeeva
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1819–1822, August, 2005.

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Ershov, B.G., Janata, E. & Gordeeva, A.V. Reduction of AgI complexes with malonate ions in aqueous solution studied by pulse radiolysis. Russ Chem Bull 54, 1874–1877 (2005). https://doi.org/10.1007/s11172-006-0051-3

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  • DOI: https://doi.org/10.1007/s11172-006-0051-3

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