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Inertness of C60 fullerene toward RO2 · peroxy radicals

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Abstract

The reactivity of fullerene C60 toward peroxy radicals RO2 · was tested by the chemiluminescence method. A comparison of the influence of C60 and known inhibitors on the kinetics of liquid-phase chemiluminescence (CL) during oxidation of a series of hydrocarbons (ethyl-benzene, cyclohexane, n-dodecane, and oleic acid) shows that the fullerene does not react with the RO2 · radicals. A sharp decrease in the CL intensity observed upon C60 addition is caused by the quenching of CL emitters with fullerene but not by inhibition of hydrocarbon oxidation.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 141 prosp. Oktyabrya, 450075, Ufa, Russian Federation

    R. G. Bulgakov, Yu. G. Ponomareva, S. I. Maslennikov, E. Yu. Nevyadovsky & S. V. Antipina

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  1. R. G. Bulgakov
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  2. Yu. G. Ponomareva
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  3. S. I. Maslennikov
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  4. E. Yu. Nevyadovsky
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1808–1811, August, 2005.

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Bulgakov, R.G., Ponomareva, Y.G., Maslennikov, S.I. et al. Inertness of C60 fullerene toward RO2 · peroxy radicals. Russ Chem Bull 54, 1862–1865 (2005). https://doi.org/10.1007/s11172-006-0049-x

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  • DOI: https://doi.org/10.1007/s11172-006-0049-x

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