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New hybrid chelating sorbents with grafted 3-aminopropionate groups based on mixed silicon, aluminum, titanium, or zirconium oxides

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Abstract

A series of new hybrid organo-inorganic sorbents with the 3-aminopropionate chelating group was synthesized. The synthesis includes the copolycondensation (sol—gel method) of tetraethoxysilane, 3-aminopropyltriethoxysilane, and several modifiers (MeSi(OEt)3, EtSi(OEt)3, Ti(OEt)4, AlONO3, ZrOCl2) followed by carboxyethylation with acrylic acid. The obtained chelating sorbents were characterized by elemental analysis, FT-IR and 1H NMR spectroscopy, and thermogravimetry. The N-carboxylated sorbents have a higher sorption capacity with respect to metal ions (0.5–0.9 mmol g−1, pH 6.3, NH4OAc, 20 °C) than the starting sorbents with the primary amino group (0.05–0.2 mmol g−1) and manifest high selectivity for copper(II) ion extraction.

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Authors and Affiliations

  1. Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences, 20 ul. S. Kovalevskoi, 620219, Ekaterinburg, Russian Federation

    Yu. G. Yatluk & O. V. Koryakova

  2. Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, 91 ul. Pervomaiskaya, 620219, Ekaterinburg, Russian Federation

    N. A. Zhuravlev

  3. A. M. Gorky Ural State University, 51 prosp. Lenina, 620083, Ekaterinburg, Russian Federation

    L. K. Neudachina

  4. Chemistry Department, Carnegi Mellon University, 4400 Fifth Avenue, Pittsburgh, PA, 15213, USA

    Yu. A. Skorik

Authors
  1. Yu. G. Yatluk
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  2. N. A. Zhuravlev
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  3. O. V. Koryakova
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  4. L. K. Neudachina
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  5. Yu. A. Skorik
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1783–1788, August, 2005.

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Yatluk, Y.G., Zhuravlev, N.A., Koryakova, O.V. et al. New hybrid chelating sorbents with grafted 3-aminopropionate groups based on mixed silicon, aluminum, titanium, or zirconium oxides. Russ Chem Bull 54, 1836–1841 (2005). https://doi.org/10.1007/s11172-006-0045-1

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  • DOI: https://doi.org/10.1007/s11172-006-0045-1

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