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Two new organo-inorganic octamolybdate anion-based materials: Hydrothermal synthesis and structure of complexes [{Cu(4,4′-bipy)}4(Mo8O26)] and (NH4)10Mn(H2O)6[(NH2C6H4COO)2(Mo8O26)]2·15H2O

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Abstract

Two new hybrid organo-inorganic compounds [{Cu(4,4′-bipy)}4(Mo8O26)] (bipy is bipyridyl) (1) and (NH4)10Mn(H2O)6[(NH2C6H4COO)2(Mo8O26)]2· 15H2O (2) were prepared under mild hydrothermal conditions and structurally characterized by single-crystal X-ray diffraction. A new type of one-dimensional network consisting of four linear chains Cu—4,4′-bipy and isolated α-octamolybdate anions was found in the complex 1 structure. Complex 2 is the first example of molybdenum oxide with a template structure involving 4-aminobenzoic acid.

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Authors and Affiliations

  1. Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, P. R. China

    Q. Zhang, C. Lu & W. Yang

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  1. Q. Zhang
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  2. C. Lu
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  3. W. Yang
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1767–1772, August, 2005.

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Zhang, Q., Lu, C. & Yang, W. Two new organo-inorganic octamolybdate anion-based materials: Hydrothermal synthesis and structure of complexes [{Cu(4,4′-bipy)}4(Mo8O26)] and (NH4)10Mn(H2O)6[(NH2C6H4COO)2(Mo8O26)]2·15H2O. Russ Chem Bull 54, 1819–1824 (2005). https://doi.org/10.1007/s11172-006-0043-3

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  • DOI: https://doi.org/10.1007/s11172-006-0043-3

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