Abstract
The reaction of the carbidocarbonyl cluster [Fe6C(CO)16]2− with ruthenium(IV) hydroxochloride Ru(OH)Cl3 was studied. At 90–100 °C, the reaction gave products of replacement of Fe atoms by Ru in the [Fe6C(CO)16]2− cluster along with degradation products. Treatment of the replacement products with FeCl3 afforded the [Fe2.96Ru3.04C(CO)17] compound (1), which was characterized by X-ray diffraction analysis. The crystals of cluster 1 are composed of two types of octahedral molecules (1a and 1b) in a ratio of 2 : 1. Molecules 1a are in general positions, and molecules 1b are located on twofold axes. In both molecules, the Fe and Ru atoms are disordered over four of six positions.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1761–1766, August, 2005.
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Gubin, S.P., Kuz'mina, L.G., Churakov, A.V. et al. Replacement of Fe atoms by Ru in a carbidocarbonyl cluster [Fe6C(CO)16]2−. Structures of reaction products. Russ Chem Bull 54, 1813–1818 (2005). https://doi.org/10.1007/s11172-006-0042-4
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DOI: https://doi.org/10.1007/s11172-006-0042-4