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Oxidation of aniline with solutions of Mo—V-phosphoric heteropolyacids

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Abstract

Mo—V-phosphoric heteropolyacids (HPA) can be used for aniline oxidation to polyaniline or 1,4-benzoquinone. At room temperature and the molar ratio HPA : aniline = 0.67, more than 95% substrate are oxidized to polyaniline. At 90–100 °C and HPA : aniline = 3, the substrate is quantitatively oxidized to 1,4-benzoquinone. Solutions of HPA are regenerated by oxygen in a separate step.

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Authors and Affiliations

  1. G. K. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 5 prosp. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation

    M. V. Simonova, E. G. Zhizhina & K. I. Matveev

  2. N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, 9 prosp. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation

    V. V. Russkikh

Authors
  1. M. V. Simonova
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  2. E. G. Zhizhina
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  3. V. V. Russkikh
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  4. K. I. Matveev
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1488–1490, June, 2005.

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Simonova, M.V., Zhizhina, E.G., Russkikh, V.V. et al. Oxidation of aniline with solutions of Mo—V-phosphoric heteropolyacids. Russ Chem Bull 54, 1532–1534 (2005). https://doi.org/10.1007/s11172-005-0442-x

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  • DOI: https://doi.org/10.1007/s11172-005-0442-x

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