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Cubane derivatives 7. Synthesis and molecular structure of 4-bromo-1-hydroxymethylcubane

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Abstract

The present study concerned with reduction of methyl 4-bromocubanecarboxylate (1) with lithium aluminum hydride and aluminum hydride in THF. An efficient procedure was developed for the synthesis of 4-bromo-1-hydroxymethylcubane (2) based on reduction of compound 1 with aluminum hydride under mild conditions. The structure of 2 was established by X-ray diffraction.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation

    V. V. Zakharov, G. P. Bugaeva, L. S. Barinova, G. V. Lagodzinskaya, L. B. Romanova & L. T. Eremenko

  2. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    G. G. Aleksandrov & I. L. Eremenko

Authors
  1. V. V. Zakharov
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  2. G. P. Bugaeva
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  3. L. S. Barinova
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  4. G. V. Lagodzinskaya
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  5. L. B. Romanova
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  6. G. G. Aleksandrov
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  7. L. T. Eremenko
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  8. I. L. Eremenko
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1461–1464, June, 2005.

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Zakharov, V.V., Bugaeva, G.P., Barinova, L.S. et al. Cubane derivatives 7. Synthesis and molecular structure of 4-bromo-1-hydroxymethylcubane. Russ Chem Bull 54, 1505–1508 (2005). https://doi.org/10.1007/s11172-005-0436-8

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  • DOI: https://doi.org/10.1007/s11172-005-0436-8

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