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Polyamidoimides with side chromophoric groups

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Abstract

A new method was elaborated for the introduction of chromophores into the side chains of polymers by esterification of polyamidoimides containing side carboxy groups with glycidyl ethers of dyes, 4-(4-nitrophenylazo)phenol and 4-(6-nitrobenzothiazol-2-ylazo)phenol. The optimum modification conditions were found that made it possible to esterify 15, 30, 50, and 90% of the carboxy groups. The synthesized polymers possess valuable physicomechanical properties (E = 2.8–3.3 GPa, σu = 69–90 MPa, εu = 38–77%) and glass transition temperatures of 115–125 °C, depending on the degree of esterification. After chromophore orientation in the corona discharge, all the polymers demonstrate nonlinear optical properties of the second order.

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Authors and Affiliations

  1. Institute of Macromolecular Compounds, Russian Academy of Sciences, 31 Bol'shoi prosp., 199004, St. Petersburg, Russian Federation

    M. Ya. Goikhman, L. I. Subbotina, I. V. Gofman, A. V. Yakimanskii, A. E. Bursian, G. N. Fedorova, A. V. Sidorovich, O. E. Praslova, N. N. Smirnov, I. V. Abalov & V. V. Kudryavtsev

  2. A. I. Ioffe Physical Technical Institute, Russian Academy of Sciences, 26 ul. Politekhnicheskaya, 194021, St. Petersburg, Russian Federation

    V. A. Lukoshkin

Authors
  1. M. Ya. Goikhman
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  2. L. I. Subbotina
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  3. I. V. Gofman
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  4. A. V. Yakimanskii
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  5. A. E. Bursian
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  6. V. A. Lukoshkin
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  7. G. N. Fedorova
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  8. A. V. Sidorovich
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  9. O. E. Praslova
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  10. N. N. Smirnov
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  11. I. V. Abalov
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  12. V. V. Kudryavtsev
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Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1438–1444, June, 2005.

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Goikhman, M.Y., Subbotina, L.I., Gofman, I.V. et al. Polyamidoimides with side chromophoric groups. Russ Chem Bull 54, 1481–1487 (2005). https://doi.org/10.1007/s11172-005-0431-0

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  • DOI: https://doi.org/10.1007/s11172-005-0431-0

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