Abstract
The high-resolution 1H and 13C NMR spectra of 1-vinylimidazole complexes with iron group metals were recorded. The contact coupling in these systems was established in the 1H and 13C NMR spectra. The applicability of the NMR spectra transformed by long-range hyperfine coupling for elucidating the molecular structure of the ligand was shown.
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References
V. K. Voronov, The Method of Paramagnetic Agents in NMR Spectroscopy, Nauka, Novosibirsk, 1989, 168 pp. (in Russian).
J. Bertini and C. Luchinat, Coord. Chem. Rev., 1996, 150, 1.
V. K. Voronov, T. E. Moskovskaya, V. I. Glukhikh, A. I. Rezvukhin, E. S. Domnina, and G. G. Skvortsova, Koord. Khim., 1979, 5, 218 [Sov. J. Coord. Chem., 1979, 5 (Engl. Transl.)].
V. K. Voronov, V. A. Shagun, V. V. Keiko, E. S. Domnina, and G. G. Skvortsova, Zhurn. Struktur. Khim., 1980, 21, 71 [J. Struct. Chem. (USSR), 1980, 21 (Engl. Transl.)].
A. A. Kashaev, E. A. Zel'bst, M. P. Demidov, Yu. L. Frolov, N. N. Chipanina, E. S. Domnina, and G. G. Skvortsova, Koord. Khim., 1978, 4, 785 [Sov. J. Coord. Chem., 1978, 4 (Engl. Transl.)].
A. D. Garnovskii, A. P. Sadimenko, O. A. Osipov, and G. V. Tsintsadze, Zhestko-myagkie vzaimodeistviya v koordinatsionnoi khimii [Soft-Hard Interactions in the Coordination Chemistry], Izd. Rostov. Univ, Rostov, 1986, 272 pp. (in Russian).
I. A. Ushakov, A. V. Afonin, V. K. Voronov, Z. V. Stepanova, L. N. Sobenina, A. I. Mikhaleva, and B. A. Trofimov, Zhurn. Organ. Khim., 2002, 38, 1836 [Russ. J. Org. Chem., 2002, 38 (Engl. Transl.)].
G. G. Skvortsova, E. S. Domnina, Yu. I. Ivlev, N. I. Chipanina, V. I. Skorobogatova, and Yu. A. Myachin, Zhurn. Obshch. Khim., 1972, 42, 596 [J. Gen. Chem. USSR, 1972, 42 (Engl. Transl.)].
E. E. Zaev, V. K. Voronov, M. S. Shvartsberg, S. F. Vasilevsky, Yu. N. Molin, and I. L. Kotjrevsky, Tetrahedron Lett., 1968, 5, 617.
G. Bodenhausen and D. J. Ruben, Chem. Phys. Lett., 1980, 69, 185.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1430–1433, June, 2005.
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Voronov, V.K., Ushakov, I.A. & Baikalova, L.V. NMR spectra of paramagnetic complexes of 1-vinylimidazole with iron group metals. Russ Chem Bull 54, 1473–1476 (2005). https://doi.org/10.1007/s11172-005-0429-7
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DOI: https://doi.org/10.1007/s11172-005-0429-7