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Synthesis and structures of new C60 fullerene derivatives containing carbonyl groups

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Abstract

The reactions of fullerene C60 with substituted haloketones, including organophosphorus haloketones, in the presence of bases afforded new methanofullerenes containing carbonyl or carbonyl and acetal groups. The structures of the resulting compounds were established by spectroscopic methods. Their electrochemical reduction and oxidation were studied by cyclic voltammetry and ESR spectroscopy. The three-dimensional structures were calculated by the PM3 and DFT/PBE/TZ2P methods.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    V. P. Gubskaya, F. G. Sibgatullina, V. V. Yanilkin, V. I. Morozov, A. V. Toropchina, V. V. Zverev, N. M. Azancheev & I. A. Nuretdinov

Authors
  1. V. P. Gubskaya
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  2. F. G. Sibgatullina
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  3. V. V. Yanilkin
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  4. V. I. Morozov
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  5. A. V. Toropchina
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  6. V. V. Zverev
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  7. N. M. Azancheev
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  8. I. A. Nuretdinov
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Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1424–1429, June, 2005.

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Gubskaya, V.P., Sibgatullina, F.G., Yanilkin, V.V. et al. Synthesis and structures of new C60 fullerene derivatives containing carbonyl groups. Russ Chem Bull 54, 1467–1472 (2005). https://doi.org/10.1007/s11172-005-0428-8

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  • DOI: https://doi.org/10.1007/s11172-005-0428-8

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