Skip to main content
SpringerLink
Log in

Fast determination of reaction kinetic parameters with the use of microwave heating. Kinetics of decomposition of organic substances with nitric acid

  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

A mathematical model for the kinetics of a chemical reaction under microwave irradiation in a close volume in the simplest approximation of the uniform temperature and pressure distribution in a system was proposed. The previously proposed dynamic method for determination of the activation energy of oxidation of organic substances with nitric acid was substantiated. According to this method, the activation energy is determined from the experimental exponential plot for the pressure in the nonisothermic system vs. inverse temperature of the reaction mixture.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Microwave Enhanced Chemistry: Fundamentals, Sample Preparation and Applications, Eds H. M. Kingston and S. J. Haswell, American Chemical Society, Washington (DC), 1997, 748 pp.

    Google Scholar 

  2. I. V. Kubrakova, Usp. Khim., 2002, 71, 327 [Russ. Chem. Rev., 2002, 71, 283 (Engl. Transl.)].

    Google Scholar 

  3. L. Perreux and A. Loupy, Tetrahedron, 2001, 57, 9199.

    Article  CAS  Google Scholar 

  4. I. V. Kubrakova, Doct. Sci. (Chem.) Thesis, Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, Moscow, 1999, 255 pp. (in Russian).

  5. I. Kubrakova, A. Formanovsky, T. Kudinova, and N. Kuz'min, Mendeleev Commun., 1998, 93.

  6. D. Lucas, Anal. Biochem., 1978, 91, 394.

    Article  CAS  Google Scholar 

  7. B. Smets, Spectrochim. Acta, 1980, 35B, 33.

    CAS  Google Scholar 

  8. I. V. Kubrakova, A. A. Formanovskii, T. F. Kudinova, and N. M. Kuz'min, Zh. Anal. Khim., 1999, 54, 520 [J. Anal. Chem., 1999, 54 (Engl. Transl.)].

    Google Scholar 

  9. P. Atkins, Physical Chemistry, Oxford University Press, Oxford, 1978.

    Google Scholar 

  10. K. W. Pratt, 41st Meeting of the Int. Soc. of Electrochemistry/J. Heyrovsky Centennial Congress on Polarography (Prague, August 22, 1990), Book of Abstrs, Prague, 1990, Tu-119.

  11. G. N. Freidlin, L. A. Golubko, and L. G. Romanova, Zh. Prikl. Khim., 1972, 45, 219 [J. Appl. Chem. USSR, 1972, 45 (Engl. Transl.)].

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, 19 ul. Kosygina, 119991, Moscow, Russian Federation

    I. V. Kubrakova & R. Kh. Khamizov

Authors
  1. I. V. Kubrakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. R. Kh. Khamizov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1371–1375, June, 2005.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kubrakova, I.V., Khamizov, R.K. Fast determination of reaction kinetic parameters with the use of microwave heating. Kinetics of decomposition of organic substances with nitric acid. Russ Chem Bull 54, 1413–1417 (2005). https://doi.org/10.1007/s11172-005-0420-3

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-005-0420-3

Key words

Search

Navigation