Skip to main content
SpringerLink
Log in

Solvation enthalpies of formamides and acetamides in a water—glycerol mixture. Additivity of thermochemical characteristics of solutions

  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The solution enthalpies of formamide and N,N-dimethyl- and diethylamides of formic and acetic acids in a water—glycerol mixed solvent were measured and the solvation enthalpies were calculated. The enthalpy coefficients of amide—glycerol pair interactions in aqueous solution were calculated. The effect of the mixture composition and the structure and properties of solutes on the enthalpic characteristics were considered. The contributions of structural fragments of the amide molecules to the enthalpic characteristics of solutions were calculated in the framework of the proposed additive scheme. This made it possible to analyze the role of nonspecific and specific solvations of the amides in solution and predict the vaporization, solution, and solvation enthalpies and enthalpy coefficients of pair interactions of experimentally unstudied N-methylformamide, N-ethylformamide, N-methyl-N-ethylformamide, N-methylacetamide, N-ethylacetamide, and N-methyl-N-ethylacetamide in a water—glycerol mixture, as well as donor numbers for these amides.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. D. V. Batov, A. M. Zaichikov, V. P. Slyusar, and V. P. Korolev, Zh. Obshch. Khim., 2001, 71, 1282 [Russ. J. Gen. Chem., 2001, 71 (Engl. Transl.)].

    Google Scholar 

  2. R. Skold, J. Suurkuusk, and I. Wadso, J. Chem. Thermodyn., 1976, 8, 1075.

    CAS  Google Scholar 

  3. J. N. Spencer, S. K. Berger, C. R. Powell, B. D. Henning, G. G. Furman, W. M. Loffredo, E. M. Rydberg, R. A. Neubert, C. T. Shoop, and D. N. Blanch, J. Phys. Chem., 1981, 85, 1236.

    Article  CAS  Google Scholar 

  4. A. Rouw and G. Somsen, J. Chem. Soc., Faraday Trans. 1, 1982, 78, 3397.

    Article  CAS  Google Scholar 

  5. A. H. Sijpkes, A. A. C. M. Oudhuia, G. Somsen, and T. N. Lilley, J. Chem. Thermodyn., 1989, 21, 343.

    CAS  Google Scholar 

  6. Yu. M. Kessler and N. A. Abakumova, Izv. Vuzov. Khim. Khim. Tekhnol. [Bulletin of Higher Educational Institutions. Chemistry and Chemical Technology], 1982, 25, 162 (in Russian).

    Google Scholar 

  7. D. V. Batov, A. M. Zaichikov, and N. G. Manin, Zh. Obshch. Khim., 2001, 71, 909 [Russ. J. Gen. Chem., 2001, 71 (Engl. Transl.)].

    Google Scholar 

  8. D. V. Batov, A. M. Zaichikov, and N. G. Manin, Zh. Obshch. Khim., 2002, 72, 1114 [Russ. J. Gen. Chem., 2001, 72 (Engl. Transl.)].

    Google Scholar 

  9. D. V. Batov and A. M Zaichikov, Zh. Obshch. Khim., 2003, 73, 545 [Russ. J. Gen. Chem., 2003, 73 (Engl. Transl.)].

    Google Scholar 

  10. V. A. Klimova, Osnovnye mikrometody analiza organicheskikh soedinenii [The Main Micromethods for Analysis of Organic Compounds], Khimiya, Moscow, 1967, 208 pp. (in Russian).

    Google Scholar 

  11. D. V. Batov, V. N. Vandyshev, V. P. Korolev, and G. A. Krestov, Zh. Fiz. Khim., 1983, 57, 253 [J. Phys. Chem. USSR, 1983, 57 (Engl. Transl.)].

    Google Scholar 

  12. Y. Marcus, Chem. Soc. Rev., 1993, 22, 409.

    Article  CAS  Google Scholar 

  13. G. Barone, G. Castronuovo, G. Della Gatta, V. Elia, and A. Iannone, Fluid Phase Equil., 1985, 21, 157.

    Article  CAS  Google Scholar 

  14. R. Sabbah, R. Chastel, and M. Laffitte, Thermochim. Acta, 1972, 5, 117.

    Article  CAS  Google Scholar 

  15. D. V. Batov, V. P. Korolyov, and G. A. Krestov, Thermochim. Acta, 1990, 169, 69.

    Google Scholar 

  16. W. K. Stephenson and R. Fuchs, Can. J. Chem., 1985, 63, 336.

    CAS  Google Scholar 

  17. R. Fuchs and W. K. Stephenson, Can. J. Chem., 1985, 63, 349.

    CAS  Google Scholar 

  18. V. P. Belousov and M. Yu. Panov, Termodinamika vodnykh rastvorov neelektrolitov [Thermodynamics of Nonelectrolyte Solutions], Khimiya, Leningrad, 1983, 264 pp. (in Russian).

    Google Scholar 

  19. G. Della Gatta, L. Stradella, and P. Venturello, J. Solut. Chem., 1981, 10, 209.

    Article  Google Scholar 

  20. F. Rocha and M. Bastos, J. Solut. Chem., 1997, 26, 989.

    CAS  Google Scholar 

  21. V. M. Tatevskii, Teoriya fiziko-khimicheskikh svoistv molekul i veshchestv [Theory of Physicochemical Properties of Molecules and Substances], Izd-vo Mosk. Gos. Univ., Moscow, 1987, 239 pp. (in Russian).

    Google Scholar 

  22. J. J. Savage and R. H. Wood, J. Solut. Chem., 1976, 5, 733.

    Article  CAS  Google Scholar 

  23. J. Konicek and I. Wadso, Acta Chem. Scand., 1971, 25, 1541.

    Article  CAS  Google Scholar 

  24. A. M. Zaichikov and N. G. Manin, Zh. Obshch. Khim., 2001, 71, 726 [Russ. J. Gen. Chem., 2001, 71 (Engl. Transl.)].

    Google Scholar 

  25. P. J. Cheek and T. N. Lilley, J. Chem. Soc., Faraday Trans. 1, 1988, 84, 1927.

    CAS  Google Scholar 

  26. A. Zielenkiewicz, Thermochim. Acta, 1984, 79, 371.

    Article  CAS  Google Scholar 

  27. J. P. Grolier, J. J. Spitzer, R. H. Wood, and I. R. Tasker, J. Solut. Chem., 1985, 14, 393.

    Article  CAS  Google Scholar 

  28. I. R. TAsker and R. H. Wood, J. Solut. Chem., 1982, 11, 295.

    CAS  Google Scholar 

  29. S. Cabani, P. Gianni, V. Mollica, and L. Lepori, J. Solut. Chem., 1981, 10, 563.

    Article  CAS  Google Scholar 

  30. Yu. M. Kessler and A. L. Zaitsev, Sol'vofobnye effekty [Solvophobic Effects], Khimiya, Leningrad, 1989, 312 pp. (in Russian).

    Google Scholar 

  31. V. Gutmann, Coordination Chemistry in Non-Aqueous Solutions, Springer-Verlag, Wienheim—New York, 1968.

    Google Scholar 

  32. Progress in Physical Organic Chemistry, Eds S. G. Cohen, A. Streitwieser, and R. W. Taft, Interscience Publishers—J. Wiley and Sons, New York—London, 1963, Vols 1, 2.

    Google Scholar 

  33. Yu. M. Kessler, P. R. Fomicheva, and N. M. Alpatova, Zh. Strukt. Khim., 1972, 13, 517 [J. Struct. Chem. USSR, 1972, 13 (Engl. Transl.)].

    CAS  Google Scholar 

  34. A. K. Lyashchenko, V. S. Khar'kin, A. S. Lileev, and V. S. Goncharov, Zh. Fiz. Khim., 1992, 66, 2256 [Russ. J. Phys. Chem., 1992, 66, 2256 (Engl. Transl.)].

    CAS  Google Scholar 

  35. N. D. Devyatkov, O. V. Betskii, V. A. Zavizion, V. A. Kudryashova, and Yu. I. Khurgin, Dokl. Akad. Nauk SSSR, 1982, 264, 1409 [Dokl. Chem., 1982 (Engl. Transl.)].

    CAS  Google Scholar 

  36. W. G. McMillan and J. E. Mayer, J. Phys. Chem., 1945, 13, 276.

    CAS  Google Scholar 

  37. J. E. Desnoyers, G. Perron, L. Avedikian, and J. P. Morel, J. Solut. Chem., 1976, 5, 631.

    CAS  Google Scholar 

  38. S. K. Suri, J. J. Spitzer, R. H. Wood, E. G. Abel, and P. T. Thompson, J. Solut. Chem., 1985, 14, 781.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Solutions Chemistry, Russian Academy of Sciences, 1 ul. Akademicheskaya, 153045, Ivanovo, Russian Federation

    D. V. Batov

  2. Ivanovo State University of Chemistry and Technology, 7 prosp. F. Engelsa, 153460, Ivanovo, Russian Federation

    D. D. Batov

Authors
  1. D. V. Batov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. D. Batov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1363–1370, June, 2005.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Batov, D.V., Batov, D.D. Solvation enthalpies of formamides and acetamides in a water—glycerol mixture. Additivity of thermochemical characteristics of solutions. Russ Chem Bull 54, 1405–1412 (2005). https://doi.org/10.1007/s11172-005-0419-9

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-005-0419-9

Key words

Search

Navigation