Skip to main content
Log in

Electron affinity and suppression effect in analysis of chlorofullerenes by MALDI mass spectrometry

Russian Chemical Bulletin Aims and scope

Abstract

Samples of the recently obtained higher chlorides of fullerenes C60 and C70 were analyzed by MALDI mass spectrometry. These systems exhibit the suppression effect of signals from the main components compared to signals of admixtures. A model was proposed to explain this effect by the Bell-Evans-Polanyi principle taking into account specific features of the structures and electron-withdrawing properties of different fullerene chlorides. The model is of general character and can be used for description of different suppression effects using MALDI mass spectrometry.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. S. I. Troyanov, N. B. Shustova, A. A. Popov, M. Feist, and E. Kemnitz, Zh. Neorg. Khim., 2004, 49, 1413 [Russ. J. Inorg. Chem., 2004, 49, 1303 (Engl. Transl.)].

    CAS  Google Scholar 

  2. S. I. Troyanov, N. B. Shustova, A. A. Popov, L. N. Sidorov, and E. Kemnitz, Angew. Chem., Int. Ed., 2005, 44, 432.

    CAS  Google Scholar 

  3. P. A. Troshin, R. N. Lyubovskaya, I. N. Ioffe, N. B. Shustova, E. Kemnitz, and S. I. Troyanov, Angew. Chem., Int. Ed., 2005, 44, 234.

    Article  CAS  Google Scholar 

  4. N. B. Shustova, A. A. Popov, L. N. Sidorov, A. P. Turnbull, E. Kemnitz, and S. I. Troyanov, Chem. Commun., 2005, 72.

  5. A. V. Streletskiy, I. V. Gol'dt, I. V. Kouvytchko, I. N. Ioffe, L. N. Sidorov, T. Drewello, S. H. Strauss, and O. V. Boltalina, Rapid Commun. Mass Spectrom., 2002, 18, 360.

    Google Scholar 

  6. A. V. Streletskiy, I. V. Kouvytchko, S. E. Esipov, and O. V. Boltalina, Rapid Commun. Mass Spectrom., 2002, 16, 99.

    Article  CAS  Google Scholar 

  7. A. V. Streletskiy, I. V. Goldt, I. V. Kouvytchko, L. N. Sidorov, O. V. Boltalina, S. E. Esipov, T. Drewello, and S. Strauss, Book of Abstracts. 6th Biennial International Workshop “Fullerenes and Atomic Clusters” (St. Petersburg, June 30–July 4, 2003), St. Petersburg, 2003, P–76.

  8. R. Knochenmuss and R. Zenobi, Chem. Rev., 2003, 103, 4412.

    Article  Google Scholar 

  9. N. B. Shustova, A. A. Popov, L. N. Sidorov, A. P. Turnbull, E. Kemnitz, and S. I. Troyanov, Chem. Commun., 2005, 1411.

  10. D. N. Laikov, Chem. Phys. Lett., 1997, 281, 151.

    Article  CAS  Google Scholar 

  11. J. P. Perdew, K. Burke, and M. Ernzerhof, Phys. Rev. Lett., 1996, 77, 3865.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

__________

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 1093–1096, May, 2005.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sidorov, L.N., Livadaris, V., Shustova, N.B. et al. Electron affinity and suppression effect in analysis of chlorofullerenes by MALDI mass spectrometry. Russ Chem Bull 54, 1121–1124 (2005). https://doi.org/10.1007/s11172-005-0368-3

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-005-0368-3

Key words

Navigation