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Synthesis of anthrathiopyrantriones by heterocyclization of alkynoyl derivatives of chloroanthraquinones

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Abstract

A procedure was developed for the synthesis of 2-substituted, including 2-alkenyl-substituted, 4H-anthra[1,2-b]thiopyran-4,7,12-triones and 4H-anthra[2,3-b]thiopyran-4,6,11-triones by cyclocondensation of vic-alkynoylchloroanthraquinones with Na2S.

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Authors and Affiliations

  1. Institute of Chemical Kinetics and Combustion, Siberian Branch, Russian Academy of Sciences, 3 ul. Institutskaya, 630090, Novosibirsk, Russian Federation

    I. D. Ivanchikova & M. S. Shvartsberg

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  1. I. D. Ivanchikova
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  2. M. S. Shvartsberg
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2205–2209, October, 2004.

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Ivanchikova, I.D., Shvartsberg, M.S. Synthesis of anthrathiopyrantriones by heterocyclization of alkynoyl derivatives of chloroanthraquinones. Russ Chem Bull 53, 2303–2307 (2004). https://doi.org/10.1007/s11172-005-0117-7

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  • DOI: https://doi.org/10.1007/s11172-005-0117-7

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