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Reactions of 1,2-ethanedithiol and 2-mercaptoethanol with unsaturated derivatives of four-coordinate phosphorus acids

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Abstract

The reaction of 1,2-ethanedithiol with diethyl vinylphosphonate in the presence of EtONa occurs as the addition of the sulfhydryl group to the β-carbon atom of the substrate to give 1 : 1 and 1 : 2 adducts. The nucleophilic addition of 2-mercaptoethanol at the β position of the multiple bond of diethyl vinyl-, diethyl allenyl-, and diethyl prop-1-ynylphosphonates involves only the sulfhydryl group.

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Authors and Affiliations

  1. Kazan State University, 18 ul. Kremlevskaya, 420008, Kazan, Russian Federation

    N. G. Khusainova, O. A. Mostovaya, E. A. Berdnikov & R. A. Cherkasov

  2. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    Yu. Ya. Efremov & D. R. Sharafutdinova

Authors
  1. N. G. Khusainova
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  2. O. A. Mostovaya
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  3. E. A. Berdnikov
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  4. Yu. Ya. Efremov
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  5. D. R. Sharafutdinova
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  6. R. A. Cherkasov
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2156–2159, October, 2004.

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Khusainova, N.G., Mostovaya, O.A., Berdnikov, E.A. et al. Reactions of 1,2-ethanedithiol and 2-mercaptoethanol with unsaturated derivatives of four-coordinate phosphorus acids. Russ Chem Bull 53, 2253–2256 (2004). https://doi.org/10.1007/s11172-005-0109-7

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  • DOI: https://doi.org/10.1007/s11172-005-0109-7

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