Abstract
Representatives of the homologous series of α,ω-diallylpermethyloligosilanes were synthesized for the first time by the reaction of α,ω-dichloropermethyloligosilanes Cl(Me2Si)nCl (n = 2–6) with allylmagnesium chloride. Fragmentation of α,ω-diallylpermethyloligosilanes under electron impact ionization was studied by mass spectrometry.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
A. M. Tsirlin and N. A. Popova, Keramikoobrazuyushchie kremniiorganicheskie polimery — polikarbosilany [Ceramic-Forming Organosilicon Polymers — Polycarbosilanes], Izd-vo NIITEKhIM, Moscow, 1990, 58 pp. (in Russian).
H. Sakurai, A. Hosomi, and M. Kumada, Tetrahedron Lett., 1968, 2469.
V. F. Mironov, V. D. Sheludyakov, and V. I. Zhun’, Zh. Obshch. Khim., 1977, 47, 1756 [J. Gen. Chem. USSR, 1977, 47 (Engl. Transl.)].
A. Yu. Osadchev, A. R. Pushkarev, Yu. Yu. Nikitina, V. V. Shamanin, and S. S. Skorokhodov, Zh. Obshch. Khim., 2000, 70, 1470 [Russ. J. Gen. Chem., 2000, 70 (Engl. Transl.)].
Yu. P. Egorov, L. A. Leites, and V. F. Mironov, Zh. Strukt. Khim., 1961, 2, 563 [J. Struct. Chem. (USSR), 1961 (Engl. Transl.)].
L. A. Leites, S. S. Bukalov, T. S. Yadritseva, B. A. Antipova, and V. V. Dement’ev, Macromolecules, 1992, 25, 2991.
M. R. Litzow and T. R. Spalding, Mass Spectrometry of Inorganic and Organometallic Compounds, Ed. M. F. Lappert, SPC, Amsterdam, 1973, 573 pp.
C. H. Middlecamp, W. Wojnowski, and R. West, J. Organomet. Chem., 1977, 140, 133.
H. G. Schuster and E. Hengge, Monatsh. Chem., 1983, 114, 1305.
Y. Nakadaira, Y. Kobayashi, and H. Sakurai, J. Organomet. Chem., 1973, 63, 79.
E. Hengge and G. Miklau, Z. Anorg. Allg. Chem., 1984, 508, 43.
NIST/EPA/NIH Mass Spectral Library, V. 1.0, National Institute of Standards and Technology, Gaithersburg (Mary land, USA), 2002.
A. I. Chernyavskii and N. A. Chernyavskaya, Izv. Akad. Nauk, Ser. Khim., 2002, 1607 [Russ. Chem. Bull., Int. Ed., 2002, 51, 1751].
Author information
Authors and Affiliations
Additional information
__________
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2129–2132, October, 2004.
Rights and permissions
About this article
Cite this article
Larkin, D.Y., Pleshkova, A.P., Kononova, E.G. et al. Synthesis and mass spectrometric study of α,ω-diallylpermethyloligosilanes. Russ Chem Bull 53, 2224–2228 (2004). https://doi.org/10.1007/s11172-005-0104-z
Received:
Issue Date:
DOI: https://doi.org/10.1007/s11172-005-0104-z