Abstract
An efficient method for methyl methacrylate radical polymerization by tri-n-propyl-, triisopropyl-, and triisobutylborane ammonia complexes, including the addition of a boron-containing initiating agent into the monomer in air, was developed. An advantage of this method is that the reaction occurs at room temperature, requires no peroxide components, and leads to polymers with enhanced thermal stability.
Similar content being viewed by others
References
V. A. Dodonov, L. S. Kochneva, I. N. Aksenova, and L. M. Terman, Vysokomol. Soedin., Ser. B, 1986, 28, 582 [Polym. Sci. USSR; Ser. B, 1986, 28 (Engl. Transl.)].
V. A. Dodonov, Zh. V. Garusova, Z. V. Orlova, and T. I. Starostina, Vysokomol. Soedin., Ser. B, 1999, 41, 1831 [Polym. Sci., Ser. B, 1999, 41, 327 (Engl. Transl.)].
O. Grummit, J. Am. Chem. Soc., 1942, 64, 1811.
G. A. Razuvaev, V. A. Dodonov, and Yu. A. Ivanova, Dokl. Akad. Nauk SSSR, 1980, 250, 119 [Dokl. Chem., 1980 (Engl. Transl.)].
V. A. Dodonov, Yu. L. Kuznetsova, and A. A. Skatova, Vysokomol. Soedin., Ser. B, 1999, 41, 1516 [Polym. Sci., Ser. B, 1999, 41, 261 (Engl. Transl.)].
V. A. Dodonov, A. A. Skatova, Yu. L. Kuznetsova, and I. I. Brezhneva, Vysokomol. Soedin., Ser. A, 2000, 42, 1478 [Polym. Sci., Ser. A, 2000, 42, 967 (Engl. Transl.)].
A. N. Nesmeyanov and R. A. Sokolik, Metody elemento-organicheskoi khimii. Bor, alyuminii, gallii, indii, tallii [Methods of Organoelement Chemistry. Boron, Aluminum, Gallium, Indium, Thallium], Nauka, Moscow, 499 pp. (in Russian).
C. H. E. Bawn, D. Margerison, and N. M. Richardson, Proc. Chem. Soc., 1959, 397.
D. V. Demchuk, Ph. D. (Chem.) Thesis, Institite of Organic Chemistry, Russian Academy of Sciences, Moscow, 1991, 130 pp. (in Russian).
F. G. Welch, J. Polymer Sci., 1962, 61, 243.
V. A. Dodonov, O. S. Morozov, D. F. Grishin, E. G. Lyutin, and N. N. Vyshinskii, Dokl. Akad. Nauk USSR, 1980, 255, 1123 [Dokl. Chem., 1980 (Engl. Transl.)].
V. A. Dodonov and I. N. Aksenova, Vysokomol. Soedin., Ser. B, 1986, 28, 422 [Polym. Sci. USSR, Ser. B, 1986, 28 (Engl. Transl.)].
W. Debski, Polymetakrylan metylu, Widawnictwa Naukowo-techniczne, Warsawa, 1972 (in Polish).
V. S. Bogdanov, Doct. Sci. (Chem.) Thesis, Institute of Organic Chemistry, USSR Academy of Sciences, Moscow, 1975, 253 pp. (in Russian).
P. Renaud and O. Cyril, Chem. Rev., 2001, 101, 3415.
N. N. Vyshinskii and V. I. Kokorev, Dokl. Akad. Nauk, SSSR, 1977, 236, 8836 [Dokl. Chem., 1977 (Engl. Transl.)].
F. A. Bovey, High Resolution NMR of Macromolecules, Academic Press, New York—London, 1972.
F. A. Bovey, J. Polym. Sci. Polym. (A) (Chem. Ed.), 1996, 34, 711.
V. A. Kabanov, Int. Symp. on Makromol. Chem. IUPAC, Budapest, 1969, 435.
V. A. Dodonov and D. F. Grishin, Vysokomol. Soedin., Ser. B, 1993, 35, 47 [Polym. Sci., Ser. B, 1993, 35, 137 (Engl. Transl.)].
A. J. Gordon and R. A. Ford, The Chemist’s Companion, Wiley-Interscience, New York, 1972.
B. M. Mikhailov, Yu. N. Bubnov, and V. G. Kiselev, Zh. Org. Khim. [Sov. J. Org. Chem.], 1966, 36, 62 (in Russian).
B. M. Mikhailov and Yu. N. Bubnov, Organoboron Compounds in Organic Synthesis, Bell and Bain Ltd., Glasgow, 1984, 781 pp.
J. Billiani, I. Amtman, T. Mayr, and K. Lederer, J. Liq. Cromatogr., 1990, 13, 2973.
R. Koster, G. Bruno, and P. Binger, Ann., 1961, 1, 644.
H. C. Brown, J. Am. Chem. Soc., 1945, 67, 374.
Author information
Authors and Affiliations
Additional information
__________
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2120–2125, October, 2004.
Rights and permissions
About this article
Cite this article
Erdyakov, S.Y., Mel’nik, O.A., Gurskii, M.E. et al. New efficient boron-containing initiators of methyl methacrylate radical polymerization. Russ Chem Bull 53, 2215–2220 (2004). https://doi.org/10.1007/s11172-005-0102-1
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/s11172-005-0102-1