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Magnetic properties of a dinuclear complex (2,3-Me2C5H3N)2Fe2(μ-OOCCMe3)4 with “China lantern” structure

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Abstract

Magnetic characteristics of the dinuclear complex (2,3-Me2C5H3N)2Fe2(μ-OOCCMe3)4 (1) were studied in the temperature interval 2–300 K. The magnetic behavior of complex 1 was interpreted in terms of the orbital-dependent exchange theory with allowance for the temperature dependence of the populations of the split 5T2g ground-state components of the FeII ions. The calculated values of the orbital-dependent exchange parameters are in good agreement with the results reported for dinuclear carboxylates of other 3d-transition metals and suggest the existence of strong ferromagnetism in some types of heterodinuclear carboxylates.

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Authors and Affiliations

  1. I. V. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Research Center, Russian Academy of Sciences, 14 ul. Fersmana, 184200, Apatity, Murmansk Region, Russian Federation

    Yu. V. Rakitin

  2. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    V. M. Novotortsev & I. L. Eremenko

  3. International Tomography Center, Siberian Branch, Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation

    V. N. Ikorskii

Authors
  1. Yu. V. Rakitin
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  2. V. M. Novotortsev
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  3. V. N. Ikorskii
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  4. I. L. Eremenko
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2035–2039, October, 2004.

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Rakitin, Y.V., Novotortsev, V.M., Ikorskii, V.N. et al. Magnetic properties of a dinuclear complex (2,3-Me2C5H3N)2Fe2(μ-OOCCMe3)4 with “China lantern” structure. Russ Chem Bull 53, 2124–2128 (2004). https://doi.org/10.1007/s11172-005-0084-z

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  • DOI: https://doi.org/10.1007/s11172-005-0084-z

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