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Structural chemistry of complexes with an encapsulated metal ion. α-Dioximate, oximehydrazonate, and dihydrazonate clathrochelates

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Abstract

The review surveys the main trends in the structural chemistry of clathrochelates: the determination of the crystal and molecular structures of various types of new complexes, their symmetry and functionality; the supramolecular organization and phase transitions of clathrochelate crystals; the structure—spectral parameter relationships and the deduction of the molecular structures; the use of X-ray diffraction data for explanation of the kinetic and thermodynamic parameters of the synthesis and decomposition of clathrochelates.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    Ya. Z. Voloshin & M. Yu. Antipin

  2. L. Ya. Karpov Institute of Physical Chemistry, 10 ul. Vorontsovo Pole, 105064, Moscow, Russian Federation

    Ya. Z. Voloshin

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  1. Ya. Z. Voloshin
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Hereinafter, the papers marked with an asterisk ✾ are dedicated to Academician Yurii Nikolaevich Bubnov on the occasion of his 70th birthday.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2009–2020, October, 2004.

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Voloshin, Y.Z., Antipin, M.Y. Structural chemistry of complexes with an encapsulated metal ion. α-Dioximate, oximehydrazonate, and dihydrazonate clathrochelates. Russ Chem Bull 53, 2097–2108 (2004). https://doi.org/10.1007/s11172-005-0080-3

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