Abstract
A method for preparation of dendrons and dendrimers with formyl groups at the terminal aromatic rings, ether bonds in the branching blocks, and ester bonds in the core of the macromolecules is proposed. A way for the selective synthesis of p-hydroxymethylbenzaldehyde is described.
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A. W. Bosman, H. M. Janssen, and E. W. Meijer, Chem. Rev., 1999, 99, 1665.
V. J. Pugh, Q. S. Hu, and L. Pu, Angew. Chem., Int. Ed., 2000, 39, 3638.
P. Bhyrapna and K. S. Suslick, J. Inorg. Biochem., 1997, 234.
S. M. Grayson and J. M. J. Frechet, Chem. Rev., 2001, 101, 3819.
J. N. H. Reek, A. P. H. J. Schenning, P. C. J. Kamer, E. W. Meijer, and P. W. N. M. van Leenwen, J. Am. Chem. Soc., 2001, 123, 8453.
I. P. Beletskaya and A. V. Chuchuryukin, Usp. Khim., 2000, 69, 699 [Russ. Chem. Rev., 2000, 69 (Engl. Transl.)].
A. G. Vitukhnovsky, M. I. Sluch, V. G. Krasovsky, and A. M. Muzafarov, Synthetic Metals, 1997, 91, 358.
Z. B. Shifrina, M. S. Averina, A. L. Rusanov, and K. Myullen, Tez. dokl. III Vserossiiskoi Karginskoi konferentsii “Polimery 2004” [Proc. III All Russia Kargin Conference “Polymers 2004”] (Moscow, January 2004), Izd-vo Mosk. Gos. Univ., 2004, 192 (in Russian).
C. J. Hawker and J. M. J. Frechet, J. Am. Chem. Soc., 1990, 112, 7638.
K. L. Wooley, C. J. Hawker, and J. M. J. Frechet, J. Am. Chem. Soc., 1991, 113, 4252.
Qing Cai, Youliang Zhao, and Fu Xi, Biomacromolecules, 2003, 4, 828.
M. B. Steffensen and E. E. Simanek, Org. Lett., 2003, 13, 2359.
Y. Yamakawa, M. Ueda, and R. Nagahata, J. Chem. Soc., Perkin Trans, 1998, 1, 4135.
M. Okazaku, I. Washio, and Yu. Shibasaki, J. Am. Chem. Soc., 2003, 125, 8120.
M. Fischer and F. Vogtle, Angew. Chem., Int. Ed., 1999, 38, 884.
J. Issberner, R. Moors, and F. Vogtle, Angew. Chem., Int. Ed., 1994, 24, 2413.
G. R. Newkome, Enfu He, and C. N. Moorefield, Chem. Rev., 1999, 99, 1689.
C. Gennari, S. Ceccarelli, and U. Piarulli, Tetrahedron, 1998, 54, 14999.
Chi Ching Mak, N. Bampos, and S. L. Darling, J. Org. Chem., 2001, 66, 4476.
H.-T. Chang, C.-T. Chen, and T. Kondo, Angew. Chem., Int. Ed., 1996, 35, 182.
C. J. Hawker and J. M. J. Frechet, J. Chem. Soc., Perkin Trans 1, 1992, 19, 2459.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1995–1999, September, 2004.
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Loim, N.M., Kelbyscheva, E.S. Synthesis of dendrimers with terminal formyl groups. Russ Chem Bull 53, 2080–2085 (2004). https://doi.org/10.1007/s11172-005-0076-z
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DOI: https://doi.org/10.1007/s11172-005-0076-z