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Structures of cationic metallacarborane complexes [(η-9-Me2S-7,8-C2B9H10)Ni(μ-Cp)Ni(η-9-Me2S-7,8-C2B9H10)]+ and [Cp*Ru(Me2S-C2B9H10)RuCp*]+

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Abstract

The structures of the metallacarborane cations [(η-9-Me2S-7,8-C2B9H10)Ni(μ-Cp)Ni(η-9-Me2S-7,8-C2B9H10)]+ (2) and [Cp*Ru(Me2S-C2B9H10)RuCp*]+ (4b) were established by X-ray diffraction analysis. These results confirmed the triple-decker structure proposed for complex 2 earlier, whereas complex 4b proved to be 13-vertex dimetallacarborane rather than the triple-decker complex, as has been suggested earlier.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    A. R. Kudinov, M. I. Rybinskaya, D. S. Perekalin, V. I. Meshcheryakov, Yu. A. Zhuravlev, P. V. Petrovskii, A. A. Korlyukov, D. G. Golovanov & K. A. Lyssenko

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  1. A. R. Kudinov
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  2. M. I. Rybinskaya
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  3. D. S. Perekalin
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  4. V. I. Meshcheryakov
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  5. Yu. A. Zhuravlev
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  6. P. V. Petrovskii
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  7. A. A. Korlyukov
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  8. D. G. Golovanov
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  9. K. A. Lyssenko
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1879–1883, September, 2004.

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Kudinov, A.R., Rybinskaya, M.I., Perekalin, D.S. et al. Structures of cationic metallacarborane complexes [(η-9-Me2S-7,8-C2B9H10)Ni(μ-Cp)Ni(η-9-Me2S-7,8-C2B9H10)]+ and [Cp*Ru(Me2S-C2B9H10)RuCp*]+ . Russ Chem Bull 53, 1958–1962 (2004). https://doi.org/10.1007/s11172-005-0056-3

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  • DOI: https://doi.org/10.1007/s11172-005-0056-3

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