Skip to main content
SpringerLink
Log in

Polymers containing phenylquinoxaline rings

  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The synthesis and properties of poly(phenylquinoxalines) containing hexafluoroisopropylidene or silylene units in the backbone are described. The polymers have been prepared by polycondensation of aromatic diamines containing preformed phenylquinoxaline rings with a dianhydride or diacid chlorides containing hexafluoroisopropylidene groups, or with a dianhydride or diacid chlorides containing silylene units. The solubility, thermal stability, film forming ability, and electric insulating, mechanical, and electroluminescent properties of the thin films are discussed and compared with those of related heterocyclic polymers. Potential applications of poly(phenylquinoxalines) are outlined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. W. Bureau, F. Bernard, and D. Broussoux, Rev. Tech. Thomson CSF, 1989, 20–21, 689.

    Google Scholar 

  2. C. E. Sroog, Prog. Polym. Sci., 1991, 16, 561.

    Article  CAS  Google Scholar 

  3. P. M. Hergenrother, High Perform. Polym., 2003, 15, 3.

    CAS  Google Scholar 

  4. E. S. Krongauz, Vysokomolekulyar. Soedinen., Ser. A, 1984, 26, 227 [Polym. Sci. USSR, Ser. A, 1984, 26 (Engl. Transl.)].

    Google Scholar 

  5. M. Bruma, in Handbook of Thermoplastics, Ed. O. Olabisi, Dekker, New York, 1997, p. 771.

    Google Scholar 

  6. F. W. Mercer and M. T. McKenzie, High Perform. Polym., 1993, 5, 97.

    Article  CAS  Google Scholar 

  7. M. Bruma, J. W. Fitch, and P. E. Cassidy, J. Macromol. Sci., Rev. Macromol. Chem. Phys., C, 1996, 36, 119.

    Google Scholar 

  8. P. E. Cassidy and J. W. Fitch, in Modern Fluoropolymers, Ed. J. Scheirs, Wiley, NewYork, 1997, p. 173.

    Google Scholar 

  9. D. A. Armitage, in Comprehensive Heterocyclic Chemistry, Ed. A. R. Katritzky, Pergamon Press, Oxford, 1984, 1, p. 573.

    Google Scholar 

  10. M. Bruma and B. Schulz, J. Macromol. Sci., Polym. Rev., C, 2001, 41, 1.

    Google Scholar 

  11. M. Bruma, A. L. Rusonov, and N. M. Belomoina, Vysokomolekulyar. Soedinen., Ser. A, 2004, 46, 1 [Polym. Sci., Ser. A, 2004, 26 (Engl. Transl.)].

    Google Scholar 

  12. V. V. Korshak, E. S. Krongauz, A. P. Travnikova, N. M. Belomoina, H. Raubach, and D. Hein, Acta Polym., 1983, 34, 213.

    Article  CAS  Google Scholar 

  13. USSR Pat. 540461, 1977; Byul. izobret., 1977, No. 37; Chem. Abstr., 1978, 88, 153223s.

  14. V. V. Korshak, E. S. Krongauz, N. M. Belomoina, S. A. Babich, M. Bruma, I. Sava, and E. Hamciuc, Acta Polym., 1988, 39, 409.

    Article  CAS  Google Scholar 

  15. M. Bruma, I. Sava, E. Hamciuc, N. M. Belomoina, and E. S. Krongauz, Angew. Makromol. Chem., 1991, 193, 113.

    Article  CAS  Google Scholar 

  16. Ger. (East) Pat. 138015, 1979; Chem. Abstr., 1980, 92, 128960e.

  17. M. Bruma, I. Sava, W. H. Daly, F. W. Mercer, N. M. Belomoina, and I. I. Negulescu, J. Macromol. Sci., Pure Appl. Chem., A, 1993, 30, 789.

    Google Scholar 

  18. C. J. Thaemlitz and P. E. Cassidy, Polymer, 1992, 32, 206.

    Article  Google Scholar 

  19. E. Hamciuc, M. Bruma, F. W. Mercer, and C. I. Simionescu, Angew. Makromol. Chem., 1993, 210, 143.

    Article  CAS  Google Scholar 

  20. M. Bruma, F. Mercer, B. Schulz, R. Dietel, J. Fitch, and P. Cassidy, High Perform. Polym., 1994, 6, 183.

    Article  CAS  Google Scholar 

  21. C. Hamciuc, E. Hamciuc, I. Sava, I. Diaconu, and M. Bruma, High Perform. Polym., 2000, 12, 265.

    Article  CAS  Google Scholar 

  22. C. J. Thaemlitz, W. J. Weikel, and P. E. Cassidy, Polymer, 1992, 33, 3278.

    Article  CAS  Google Scholar 

  23. C. Hamciuc, E. Hamciuc, F. W. Mercer, N. M. Belomoina, and M. Bruma, High Perform. Polym., 1996, 8, 445.

    Article  CAS  Google Scholar 

  24. J. R. Pratt and S. F. Thames, J. Org. Chem., 1973, 38, 4271.

    Article  CAS  Google Scholar 

  25. E. Hamciuc, B. Schulz, T. Kopnick, Y. Kaminorz, and M. Bruma, High Perform. Polym., 2002, 14, 63.

    Article  CAS  Google Scholar 

  26. N. D. Ghatge and J. Y. Jadhav, Synt. React. Inorg. Met. — Org. Chem., 1984, 14, 83.

    CAS  Google Scholar 

  27. M. Bruma, B. Schulz, T. Kopnick, and J. Robison, High Perform. Polym., 2000, 12, 429.

    Article  CAS  Google Scholar 

  28. B. Schulz, E. Hamciuc, T. Kopnick, Y. Kaminorz, and M. Bruma, Macromol. Symp., 2003, 199, 391.

    Article  CAS  Google Scholar 

  29. M. Bruma, E. Hamciuc, B. Schulz, T. Kopnick, B. Stiller, and F. Mercer, Polymer, 1999, 40, 6865.

    Article  CAS  Google Scholar 

  30. E. Hamciuc, M. Bruma, F. W. Mercer, N. M. Belomoina, and C. I. Simionescu, Angew. Makromol. Chem., 1995, 227, 19.

    Article  CAS  Google Scholar 

  31. M. Bruma, C. Hamciuc, E. Hamciuc, F. Mercer, N. Belomoina, and B. Schulz, Macromol. Symp., 1997, 122, 303.

    CAS  Google Scholar 

  32. E. Hamciuc, C. Hamciuc, I. Sava, and M. Bruma, Eur. Polym. J., 2001, 37, 287.

    Article  CAS  Google Scholar 

  33. I. Sava, M. Bruma, N. M. Belomoina, and F. W. Mercer, Angew. Makromol. Chem., 1993, 211, 113.

    Article  CAS  Google Scholar 

  34. I. Sava, M. Bruma, B. Schulz, F. Mercer, V. N. Reddy, and N. M. Belomoina, J. Appl. Polym. Sci., 1997, 65, 1533.

    Article  CAS  Google Scholar 

  35. I. Sava, M. Szesztay, M. Bruma, F. Mercer, and B. Schulz, Angew. Makromol. Chem., 1997, 253, 169.

    CAS  Google Scholar 

  36. M. Bruma, B. Schulz, T. Kopnick, R. Dietel, B. Stiller, F. Mercer, and V. N. Reddy, High Perform. Polym., 1998, 10, 207.

    CAS  Google Scholar 

  37. M. Bruma, B. Schulz, T. Kopnick, B. Stiller, N. Belomoina, and F. Mercer, Eur. Polym. J., 1999, 35, 1253.

    CAS  Google Scholar 

  38. M. Bruma, B. Schulz, T. Kopnick, B. Stiller, and F. Mercer, Mater. Sci. Eng. C, 1999, 8–9, 361.

    Google Scholar 

  39. K. A. Voloshchuk, G. M. Tseitlin, A. B. Blyumenfeld, N. S. Zabelnikov, and A. A. Atrushkevich, Vysokomolekulyar. Soedineniya, Ser. A, 1989, 31, 295 [Polym. Sci. USSR, Ser. A, 1989, 31 (Engl. Transl.)].

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Macromolecular Chemistry, Aleea Gr. Ghica Voda 41 A, Iasi, 700487, Romania

    M. Bruma, E. Hamciuc & I. Sava

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    N. M. Belomoina

Authors
  1. M. Bruma
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. Hamciuc
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. Sava
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. M. Belomoina
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1739–1748, September, 2004.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bruma, M., Hamciuc, E., Sava, I. et al. Polymers containing phenylquinoxaline rings. Russ Chem Bull 53, 1813–1823 (2004). https://doi.org/10.1007/s11172-005-0041-x

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-005-0041-x

Key words

Search

Navigation