Abstract
The composition and formation kinetics of erosion products of the metallic charge (aluminum, iron) in an electric-discharge reactor operating at an open-circuit voltage of 500–1000 V, peak pulse current of 250 A, and pulse energy of 0.5–1 J were studied. Dispersion products of the charge were subjected to electron-microscopic and X-ray phase analyses. The energy yield of erosion products was determined by chemical analysis to be hundreds of times the calculated yields of electrolysis. The erosion kinetics was studied and the mechanism of erosion was considered.
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REFERENCES
USSR Inventor's Certificate no. 70 000.
Namitokov, K.K., in Fizicheskie osnovy elektroiskrovoi obrabotki metallov (Physical Foundations of Electric-Spark Treatment of Metals), Moscow: Nauka, 1966, pp. 86–108.
Goryachev, V.L., Korobochko, V.Yu., Kulishevich, A.I., et al., Izv. Ross. Akad. Nauk, Ser. Fiz., 1999, no. 11, pp. 2294–2297.
Goryachev, V.L., Ufimtsev, A.A., and Khodakovskii, A.M., Pis'ma Zh. Tekh. Fiz., 1997, vol. 23, no.10, pp. 25–29.
Fominskii, L.P., Elektron. Obrab. Mater., 1980, no. 1, pp. 46–49.
Zubenko, A.A. and Yushchishina, A.N., Elektron. Obrab. Mater., 2001, no. 6, pp. 60–65.
Shamanskii, V.V., Danilenko, N.B., and Gulak, N.V., in Osnovnye vodokhozyaistvennye problemy i puti ikh resheniya. K 100-letiyu Tomskogo vodoprovoda: Materialy nauchno-prakticheskoi konferentsii (Main Hydroeconomic Problems and Ways of Their Solution. To Centennial Anniversary of Tomsk Water-Supply System: Proc. Scientific and Practical Conf.), Tomsk: Tomskvodokanal, 2005, pp. 40–42.
Lyashko, A.P., Medvinskii, A.A., Savel'ev, G.G., et al., Kinet. Katal., 1990, vol. 31, no.4, pp. 967–972.
Bairamov, R.K., Zh. Prikl. Khim., 2003, vol. 76, no.5, pp. 771–773.
Bairamov, R.K., Zh. Prikl. Khim., 2003, vol. 76, no.7, pp. 1067–1070.
Unifitsirovannye metody analiza vod (Unified Methods for Analysis of Water), Lur'e, Yu.Yu., Ed., Moscow: Khimiya, 1973.
Yavorovskii, N.A., Izv. Vyssh. Uchebn. Zaved., Ser. Fiz., 1996, no. 4, pp. 114–136.
Kotov, Yu.A., in Trudy Vserossiiskoi konferentsii “Fizikokhimiya ul'tradispersnykh sistem” (Proc. Russian Conf. “Physical Chemistry of Ultradispersed Systems”), Moscow: Mosk. Inzh.-Fiz. Inst., 1999, pp. 60–66.
Savel'ev, G.G., Shamanskii, V.V., and Lerner, M.I., Izv. Tomsk. Politekh. Univ., 2005, vol. 308, no.1, pp. 97–102.
Piskarev, I.M., Zh. Fiz. Khim., 2000, vol. 74, no.3, pp. 546–551.
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Translated from Zhurnal Prikladnoi Khimii, Vol. 78, No. 9, 2005, pp. 1463–1468.
Original Russian Text Copyright © 2005 by Danilenko, Savel'ev, Yavorovskii, Yurmazova, Galanov, Balukhtin.
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Danilenko, N.B., Savel'ev, G.G., Yavorovskii, N.A. et al. Composition and Formation Kinetics of Erosion Products of the Metallic Charge in an Electric-Discharge Reactor. Russ J Appl Chem 78, 1438–1443 (2005). https://doi.org/10.1007/s11167-005-0534-2
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DOI: https://doi.org/10.1007/s11167-005-0534-2